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    • 专利摘要:
    A self-invertible inverse latex comprising, as an inverter agent, ten-sioactive species of the family of polyglycerol esters; their use as a thickening and / or emulsifying and / or stabilizing agent of a topical cosmetic, dermopharmaceutical or pharmaceutical composition, and topical cosmetic, dermopharmaceutical or pharmaceutical compositions comprising them. A novel surfactant composition comprising polyglycerol esters.
    公开号:FR3078709A1
    申请号:FR1851933
    申请日:2018-03-06
    公开日:2019-09-13
    发明作者:Miruna Bodoc；Jerome Guilbot；Georges Dacosta；Aurelie Pierre
    申请人:Societe dExploitation de Produits pour les Industries Chimiques SEPPIC SA；
    IPC主号:
    专利说明:

    The invention relates to self-reversible reverse latexes comprising, as a reversing agent, a surfactant composition comprising polyglycerol esters and glycerol and / or glycerol oligomers, the use of said self-reversible reverse latexes as thickeners used for preparing cosmetic formulations or pharmaceuticals for topical use, as well as said formulations thus prepared.
    Cosmetic and pharmaceutical compositions for topical use, comprising polar phases such as, for example, aqueous, alcoholic, hydro-alcoholic or hydro-glycolic phases, frequently require the use of rheology-modifying polymers to increase the viscosity of said polar phases, and more generally to give them specific rheological behavior. The rheology modifiers provide both an increase in the viscosity of the polar phase, as well as a certain consistency and / or a stabilizing effect of the composition for topical use to be thickened.
    Among the rheology modifying agents which can be used for the preparation of these compositions for topical use, there are synthetic polymers such as for example anionic or cationic polyelectrolytes, linear or branched, crosslinked or noncrosslinked, come in two physical forms, the powder form and the liquid form.
    Said cosmetic and pharmaceutical compositions for topical use are generally in the form of aqueous gels, hydroalcoholic gels, hydro-glycolic gels, emulsions or micro-emulsions or nano-emulsions of the water-in-oil type or of oil-in-water or water-in-oil-in-water or oil-in-water-in-oil type.
    Among the anionic, or cationic, or ampholyte, linear or branched, crosslinked or non-crosslinked polyelectrolytes which are in a liquid form, there are those known under the name of “self-reversible reverse latexes”, which are emulsions of the water- in-oil comprising the polyelectrolyte, an aqueous phase, a fatty phase composed of at least one oil, at least one emulsifier of the water-in-oil type, at least one emulsifier of the oil-in-water type. In the processes for preparing self-reversible reverse latexes by carrying out radical polymerization in reverse emulsion, the oil-in-water type surfactants are added at the end of the polymerization step. Their addition is intended to modify and regulate the hydrophilic-lipophilic balance of the water-in-oil emulsion comprising the polymer (also called “reverse latex”) so as to obtain a mixture which, once added in a polar phase like for example water, will change direction of emulsion to pass from the water-in-oil form to the oil-in-water form, allowing then to bring the previously prepared polymer into contact with the polar phase to be thickened. During such a physical phenomenon, the crosslinked and / or branched polyelectrolyte type polymer deploys in said polar phase and forms a three-dimensional network allowing the polar phase to swell, which is manifested by an increase in the viscosity of this phase. polar. The mixture comprising the "reverse latex" and the oil-in-water type surfactant is called self-reversible reverse latex and said oil-in-water surfactant is called "reverser" or "reversing agent".
    The reversing agents commonly used for the preparation of self-reversing reverse latexes are oil-in-water type surfactants which have a HLB (Hydrophilic Lipophilic Balance) value high enough to allow the preparation of oil-type emulsions. -in stable water, generally greater than 9 and less than 16. They generally comprise a hydrophilic part consisting of a chain of ethylene oxide units and a part consisting of an aliphatic hydrocarbon chain of hydrophobic nature. Among these reversing agents are:
    - Ethoxylated fatty alcohols, of which the aliphatic hydrocarbon chain contains from 8 to 14 carbon atoms and of which the number of ethylene oxide units is between 5 and 40, for example lauric ethoxylated alcohol with 7 moles of ethylene oxide (INCI name: Laureth-7), or tridecyl alcohol containing 6 moles of ethylene oxide (INCI name: trideceth-6);
    - The ethoxylated sorbitan esters, the hydrocarbon aliphatic chain of which has 12 to 22 carbon atoms and the number of ethylene oxide units of which is between 5 and 40, for example the ethoxylated sorbitan oleate at 20 moles ethylene oxide sold under the trade name Montanox ™ 80, or sorbitan laurate ethoxylated to 20 moles of ethylene oxide sold under the trade name Montanox ™ 20;
    - Ethoxylated alkylphenols, for example ethoxylated nonylphenols and ethoxylated octylphenols; or
    - Ethoxylated castor oils, for example castor oil ethoxylated with 40 moles of ethylene oxide sold under the brand name SIMULSOL ™ OL 50.
    The evolution of consumer requirements and regulatory provisions lead cosmetic formulators to reduce the proportion of ingredients containing ethylene oxide units in their formulations. There is therefore a need to prepare reverse self-reversible latexes free of ethoxylated surfactants as reversing agents.
    French patent applications published under the numbers 2 794 034,
    794,124, 2,808,447, 2,808,446 and 2,810,883 describe the use of alkyl polyglycosides, the alkyl hydrocarbon chain of which has from one to thirty carbon atoms as reversing agents for preparing self-reversible reverse latexes, such as for example mixtures of alkyl polyglucosides in which the hydrocarbon alkyl chains are decyl, dodecyl and tetradecyl chains such as the mixture sold under the brand name SIMULSOL ™ SL 10, dodecyl, tetradecyl and hexadecyl chains such as the mixture sold under the name SIMULSOL ™ SL 26 brand, octyl and decyl chains as the mixture sold under the brand name SIMULSOL ™ SL 8, or the undecylenyl chain as the mixture sold under the brand name SIMULSOL ™ SL 11W.
    However, the use of such compounds for preparing self-reversible reverse latexes must be carried out at a temperature above their melting point, generally at 70 ° C., which poses problems of increasing the viscosity of the latex. reverse and causes a certain destabilization of said prepared self-reversible reverse latex. In some cases, it is carried out by diluting said alkyl polyglycosides in water beforehand in order to have a liquid form which can be handled at room temperature. This sometimes has the consequence of reducing the rate of inversion of said self-reversible reverse latexes in the polar phases to be thickened, and therefore of decreasing the productivity of the processes for preparing cosmetic formulations comprising such thickening agents.
    The international application published under the number WO 2009/156691 discloses the use of polyglycerol esters as reversing agents for preparing self-reversible reverse latexes, for example decaglycerol esters such as decaglycerol monolaurate, decaglycerol oleate, decaglycerol monocaprylate or decaglycerol monomyristate. However, their use leads to self-reversible reverse latexes for which the rate of inversion in the polar phases to be thickened is too slow and even decreases when the self-reversible reverse latex is stored after its preparation for more than a month. preparation.
    The inventors have therefore sought to develop a new oil-in-water type inverting surfactant system, compatible with the environmental standards in force, by being in particular free of alkylene oxide patterns which make it possible to prepare auto reverse latexes. -invertible:
    - which can be used easily and in particular which can be pumped at 25 ° C, which have a viscosity less than or equal to 8,000 mPa.s, preferably less than or equal to 5,000 mPa.s, viscosity measured at 25 ° C using a Brookfield RVT viscometer and mobile no. 3 at a speed of 20 revolutions / minute,
    - which have a smooth appearance, free from grains or lumps, and
    - which have good reversing properties in polar phases, that is to say inducing a fast and reliable reversing speed.
    The subject of the invention is therefore a self-reversible reverse latex of a crosslinked anionic polyelectrolyte (P) comprising, for 100% molar:
    (ai) - of a proportion greater than or equal to 30 mol% and less than or equal to 100 mol%, of monomeric units derived from 2-methyl acid 2 - [(1 -oxo 2-propenyl) amino] 1 -propanesulfonic in free or partially or totally salified acid form;
    (a 2 ) - optionally of a proportion greater than 0 mol% and less than or equal to 70 mol%, of monomeric units derived from at least one monomer chosen from the elements of the group consisting of acrylic acid, the methacrylic acid, 2-carboxyethyl acrylic acid, itaconic acid, maleic acid, 3-methyl 3 [(1-oxo 2-propenyl) amino] butanoic acid, the carboxylic function of said monomers being in acid form free, partially salified or totally salified and / or from the elements of the group consisting of (2-hydroxyethyl acrylate), (2,3-dihydroxy propyl acrylate), (2-hydroxy ethyl methacrylate) , (2,3-dihydroxypropyl) methacrylate, or vinyl pyrrolidone;
    (a 3 ) - of a proportion greater than 0 mol% and less than or equal to 1 mol% of monomeric units derived from at least one diethylene or polyethylene crosslinking monomer (AR);
    the sum of said molar proportions in monomeric units according to ai), a 2 ) and a 3 ) being equal to 100% molar;
    said self-reversible reverse latex being a water-in-oil type emulsion (E) comprising for 100% of its mass:
    a) - from 10% by mass to 90% by mass, of said crosslinked anionic polyelectrolyte (P);
    b) - From 5% by mass to 50% by mass, of a fatty phase consisting of at least one oil (H),
    c) - From 1% by mass to 50% by mass of water,
    d) - From 0.5% by mass to 10% by mass of an emulsifier system of the water-oil (Si) type, and
    e) - From 2% by mass to 10% by mass of an emulsifying system of the oil-in-water type (S 2 );
    the sum of the mass proportions of compounds according to a), b), c), d) and e) being equal to 100% by mass;
    said self-reversible reverse latex being characterized in that said oil-in-water type emulsifying system (S 2 ) comprises for 100% of its mass:
    f) - A proportion greater than or equal to 50% by mass and less than or equal to 100% of a composition (Ce) which comprises for 100% of its mass:
    ei) - From 10% by mass to 60% by mass, more particularly from 15% by mass to 60% by mass and very particularly from 15% by mass to 50% of at least one compound of formula (I):
    HO- [CH 2 -CH (OH) -CH 2 -O] n -H (I) wherein n represents an integer greater than or equal to one and less than or equal to fifteen;
    e 2 ) - From 40% by mass to 90% by mass, more particularly from 40% by mass to 85% by mass and very particularly from 50% by mass to 85% by mass of at least one compound of formula (II):
    Ri- (C = O) - [O-CH 2 -CH (OH) -CH 2 ] p -OH (II), in which p, different or identical to n, represents an integer greater than or equal to one and less or equal to fifteen; and in which the group Ri- (C = O) - represents a saturated or unsaturated, linear or branched aliphatic radical, comprising from six to twenty two carbon atoms, and optionally e 3 ) - Up to 30% by mass, more particularly of 0% by mass to 25% by mass and very particularly from 0% by mass to 20% by mass of at least one composition (Cn) represented by formula (III):
    HO- [CH 2 -CHOH-CH 2 -O-] q - (G) r -H (III), in which q different or identical to n, represents an integer greater than or equal to one and less than or equal to 3 , G represents the remainder of a reducing sugar and r represents a decimal number greater than or equal to 1.05 and less than or equal to 5.00, said composition (Cn) consisting of a mixture of the compounds of formulas (III), ( lll 2 ), (lll 3 ), (IUI) and (lll 5 ):
    HO- [CH 2 -CHOH-CH 2 -O-] q -O- (G) iH (llh),
    HO- [CH 2 -CHOH-CH 2 -O-] q -O- (G) 2 -H (lll 2 ),
    HO- [CH 2 -CHOH-CH 2 -O-] q -O- (G) 3 -H (lll 3 ),
    HO- [CH 2 -CHOH-CH 2 -O-] q -O- (G) 4 -H (lll 4 ),
    HO- [CH 2 -CHOH-CH 2 -O-] q -O- (G) 5 -H (lll 5 ), in molar proportions as so-called compounds of formulas (llh), (lll 2 ), (lll 3 ), (lll 4 ) and (lll 5 ) respectively equal to a b a 2 , a 3 , a 4 and a 5 , such that the sum (ai + a 2 + a 3 + a 4 + a 5 ) is equal to one , and that the sum (ai + 2a 2 + 3a 3 + 4a 4 + 5a 5 ) is equal to r;
    the sum of the mass proportions of compounds according to ei), e 2 ) and e 3 ) being equal to 100% by mass.
    Within the meaning of the present invention, by crosslinked anionic polyelectrolyte (P), is meant for the polymer (P), a nonlinear polyelectrolyte which is in the form of a three-dimensional network insoluble in water, but swellable at l water and then leading to the production of a chemical gel.
    Within the meaning of the present invention, the term “salified” indicates that the acid function present in a monomer is in an anionic form associated in the form of a salt with a cation, in particular the salts of alkali metals, such as sodium cations or potassium, or as the nitrogenous base cations such as the ammonium salt, the lysine salt or the monoethanolamine salt (HOCH 2 -CH 2 -NH 4 + ). They are preferably sodium or ammonium salts.
    According to a particular aspect of the present invention, said self-reversible reverse latex as defined above comprises from 20% by mass to 90% by mass, and more particularly from 30% by mass to 90% by mass, more particularly from 30% by ... 80% by mass, and even more particularly from 33% by mass to 80% by mass of said crosslinked anionic polyelectrolyte (P).
    According to another particular aspect of the present invention, the molar proportion in monomeric units derived from 2-methyl 2 - [(1-oxo 2-propenyl) amino] 1-propanesulfonic acid in free or partially or fully salified acid form present in said crosslinked anionic polyelectrolyte (P) is greater than or equal to 32 mol% and less than or equal to 100 mol%, more particularly greater than or equal to 40 mol% and less than or equal to 100 mol%.
    According to a particular aspect of the present invention, 2-methyl 2 - [(1-oxo 2propenyl) amino] 1-propanesulfonic acid is in the form of sodium or ammonium salt.
    According to another particular aspect of the present invention, said crosslinked anionic polyelectrolyte (P) comes from polymerization, for 100% molar:
    (ai) - of a proportion greater than or equal to 32 mol% and less than 100 mol%, more particularly greater than or equal to 40 mol% and less than or equal to 100 mol%, of monomeric units derived from a monomer having a strong acid function, partially salified or totally salified, more particularly of a sodium salt or an ammonium salt of 2-methyl 2 - [(1-oxo 2-propenyl) amino] 1-propanesulfonic acid; and (a 2 ) - of a proportion greater than 0 mol% and less than or equal to 68 mol%, more particularly greater than 0 mol% and less than or equal to 60 mol%, of monomeric units derived from at least one monomer selected from the group consisting of acrylic acid, methacrylic acid, 2-carboxyethyl acrylic acid, itaconic acid, maleic acid, 3-methyl acid 3 - [(1-oxo 2-propenyl) amino] butanoic, the carboxylic function of said monomers being in acid form, partially salified or totally salified, and / or among the elements of the group consisting of (2-hydroxyethyl acrylate), ( 2,3-dihydroxy propyl), (2-hydroxyethyl) methacrylate, (2,3-dihydroxypropyl) methacrylate, and vinyl pyrrolidone; and (a 3 ) - of a proportion greater than 0 mol% and less than or equal to 1 mol% of monomeric units derived from at least one diethylene or polyethylene crosslinking monomer (AR); it being understood that the sum of the molar proportions of the monomeric units (ai), (a 2 ) and (a 3 ) is equal to 100%.
    By at least one diethylene or polyethylene crosslinking monomer (AR), we denote, in the definition of said crosslinked anionic polyelectrolyte (P), we denote in particular a chosen monomer methylene-bis (acrylamide), ethylene glycol dimethacrylate, diacrylate diethylene glycol, ethylene glycol diacrylate, diallyl urea, triallylamine, trimethylol propanetriacrylate or methylene bis (acrylamide) or a mixture of these compounds, diallyoxyacetic acid or a salt thereof, such as sodium diallyloxyacetate, or a mixture of these compounds; and more particularly a monomer chosen from ethylene glycol dimethacrylate, triallylamine, trimethylol propanetriacrylate or methylene-bis (acrylamide) or a mixture of these compounds.
    According to another particular aspect, said crosslinking monomer (AR) is used in a molar proportion of less than or equal to 0.5%, more particularly less than or equal to 0.25% and very particularly less than or equal to 0.1 %; it is more particularly greater than or equal to 0.005 mol%.
    According to another particular aspect of the present invention, said crosslinked anionic polyelectrolyte (P) is a homopolymer of 2-methyl 2 - [(1-oxo 2-propenyl) amino] 1-propanesulfonic acid partially or totally salified in the form of sodium or ammonium salt, crosslinked with triallylamine and / or methylene-bis (acrylamide), a copolymer of 2-methyl 2 - [(1-oxo 2-propenyl) amino] 1-propanesulfonic acid and partially or fully salified acrylic acid in the form of the sodium salt or the ammonium salt, crosslinked with triallylamine and / or methylene-bis (acrylamide); a copolymer of 2-methyl 2 - [(1-oxo 2-propenyl) amino] 1-propanesulfonic acid (y) partially or totally salified in the form of the sodium salt, and of acrylic acid (δ) partially or totally salified in the form of sodium salt in a molar ratio (γ) / (δ) greater than or equal to 30/70 and less than or equal to 90/10; crosslinked with triallylamine and / or methylene-bis (acrylamide); or a copolymer of 2-methyl 2 - [(1-oxo 2-propenyl) amino] 1-propanesulfonic acid (y) partially or totally salified in the form of sodium salt, and acrylic acid (ô) partially or totally salified in the form of sodium salt in a molar ratio (y) / (ô) greater than or equal to 40/60 and less than or equal to 90/10, crosslinked by triallylamine and / or methylene-bis (acrylamide) .
    By oil (H) is meant in the definition of said self-reversible reverse latex, in particular:
    - Linear alkanes containing from eleven to nineteen carbon atoms;
    - Branched alkanes, containing from seven to forty carbon atoms, such as isododecane, isopentadecane, isohexadecane, isoheptadecane, isooctadecane, isononadecane or isoeicosane), or mixtures of certain d 'between them like those mentioned below and identified by their INCI name: C 7 - 8 isoparaffin, C 8 . 9 isoparaffin, C 9 -n isoparaffin, C9-12 isoparaffin, C 9 -i 3 isoparaffin, C 9 -i 4 isoparaffin, C 9 -i 6 isoparaffin, C10-11 isoparaffin, C10-12 isoparaffin, C10-13 isoparaffin, C11-12 isoparaffin, C11-13 isoparaffin, C11-14 isoparaffin, C12-14 isoparaffin, C12-20 isoparaffin, C13-14 isoparaffin, C13-16 isoparaffin;
    - Cyclo-alkanes optionally substituted by one or more linear or branched alkyl radicals;
    - White mineral oils, such as those sold under the following names: Marcol ™ 52, Marcol ™ 82, Drakeol ™ 6VR, Eolane ™ 130, Eolane ™ 150;
    - Hemisqualane (or 2,6,10-trimethyl-dodecane; CAS number: 3891-98-3), squalane (or 2,6,10,15,19,23-hexamethyltetracosane), hydrogenated polyisobutene or hydrogenated polydecene;
    - Mixtures of alkanes comprising from 15 to 19 carbon atoms, said alkanes being linear alkanes, branched alkanes and cyclo-alkanes, and more particularly the mixture (M1) which comprises for 100% of its mass, a proportion mass in branched alkanes greater than or equal to 90% and less than or equal to 100%; a mass proportion of linear alkanes greater than or equal to 0% and less than or equal to 9%, and more particularly less than 5% and a mass proportion of cyclo-alkanes greater than or equal to 0% and less than or equal to 1%, by example the mixtures sold under the names Emogreen ™ L15 or Emogreen ™ L19;
    - The fatty alcohol ethers of formula (IV):
    Ζι-Ο-Ζ 2 (IV), in which Zi and Z 2 which are identical or different, represent a linear or branched alkyl radical containing from five to eighteen carbon atoms, for example dioctyl ether, didecyl ether, didodecyl ether, dodecyl octyl ether, dihexadecyl ether, (1,3-dimethyl butyl) tetradecyl ether, (1,3-dimethyl butyl) hexadecyl ether, bis (1,3-dimethyl butyl) ether or dihexyl ether.
    - Mono-esters of fatty acids and alcohols of formula (V):
    R'i- (C = O) -O-R ' 2 (V), in which R'i- (C = O) represents an acyl radical, saturated or unsaturated, linear or branched, comprising from eight to twenty-four atoms of carbon, and R'2 represents, independently of R'i, a saturated or unsaturated, linear or branched hydrocarbon chain containing from one to twenty-four carbon atoms, for example methyl laurate, ethyl laurate, propyl laurate , isopropyl laurate, butyl laurate, 2butyl laurate, hexyl laurate, methyl cocoate, ethyl cocoate, propyl cocoate, isopropyl cocoate, butyl cocoate, 2-butyl cocoate, cocoate of hexyl, methyl myristate, ethyl myristate, propyl myristate, isopropyl myristate, butyl myristate, 2-butyl myristate, hexyl myristate, octyl myristate, methyl palmitate, ethyl palmitate, propyl palmitate, isopropyl palmitate, butyl palmitate, 2-butyl palmitate, hexyl palmitate , octyl palmitate, methyl oleate, ethyl oleate, propyl oleate, isopropyl oleate, butyl oleate, 2-butyl oleate, hexyl oleate, octyl oleate, methyl stearate, ethyl stearate, propyl stearate, isopropyl stearate, butyl stearate, 2-butyl stearate, stearate hexyl, octyl stearate, methyl isostearate, ethyl isostearate, propyl isostearate, isopropyl isostearate, butyl isostearate, 2-butyl isostearate, hexyl isostearate, isostearyl isostearate;
    - The di-esters of fatty acids and of glycerol of formula (VI) and of formula (VII):
    R ' 3 - (C = O) -O-CH 2 -CH (OH) -CH 2 -O- (C = O) -R' 4 (VI)
    R ' 5 - (C = O) -O-CH 2 -CH [O- (C = O) -R' 6 ] -CH 2 -OH (VII), formulas (VI) (VII) in which R ' 3 - (C = O), R ' 4 - (C = O), R' 5 - (C = O), R ' 6 - (C = O), identical or different, represent an acyl group, saturated or unsaturated, linear or branched, having from eight to twenty-four carbon atoms;
    - The tri-esters of fatty acids and glycerol of formula (VIII):
    R ' 7 - (C = O) -O-CH 2 -CH [O- (C = O) -R ” 8 ] -CH 2 -O- (C = O) -R” 9 (VIII), in which R ' 7 - (C = O), R' 8 - (C = O) and R ' 9 - (C = O), identical or different, represent an acyl group, saturated or unsaturated, linear or branched, comprising eight to twenty-four carbon atoms.
    According to another particular aspect of the present invention, said oil (H) is chosen from undecane, tridecane, isododecane or isohexadecane, mixtures of alkanes and isoalkanes and cycloalkanes such as the mixture (Mi ) as defined above and the mixtures sold under the names Emogreen ™ L15, Emogreen ™ L19, Emosmart ™ L15, Emosmart ™ L19, Emosmart ™ V21, lsopar ™ Lou Isopar ™ M; white mineral oils sold under the names Marcol ™ 52, Marcol ™ 82, Drakeol ™ 6VR, Eolane ™ 130 or Eolane ™ 150; hemisqualane, squalane, hydrogenated polyisobutene or hydrogenated polydecene; dioctyl ether or didecyl ether; isopropyl myristate, hexyl palmitate, octyl palmitate, isostearyl isostearate, octanoyl / decanoyl triglyceride, hexadecanoyl / octadecanoyl triglyceride, triglycerides from rapeseed oil, sunflower oil, linseed oil or palm oil.
    In said self-reversible reverse latex which is the subject of the present invention, the water-in-oil type emulsifying system (Si) consists either of a single emulsifying surfactant or of a mixture of emulsifying surfactants, provided that said emulsifying system (Si) resulting has an HLB value low enough to induce the formation of water-in-oil type emulsions.
    As an emulsifying surfactant of the water-in-oil type, there are for example the esters of anhydro hexitol and of aliphatic carboxylic acids, linear or branched, saturated or unsaturated, comprising from 12 to 22 carbon atoms optionally substituted with one or several hydroxyl groups, and more particularly the anhydro hexitol esters chosen from anhydro-sorbitols and anhydro-mannitols and from aliphatic carboxylic acids, linear or branched, saturated or unsaturated, containing from 12 to 22 carbon atoms optionally substituted with one or more hydroxyl groups.
    According to another particular aspect of the present invention, said water-in-oil emulsifier system (Si) is chosen from the elements of the group consisting of sorbitan laurate, for example that marketed under the name Montane ™ 20, palmitate sorbitan, for example that marketed under the name Montane ™ 40, sorbitan stearate, for example that marketed under the name Montane ™ 60, sorbitan oleate, for example that marketed under the name Montane ™ 80, sesquioleate sorbitan, for example that marketed under the name Montane ™ 85, sorbitan trioleate, for example that marketed under the name Montane ™ 83, sorbitan isolaurate, sorbitan isostearate, for example that marketed under the name Montane ™ 70, mannitan laurate, mannitan oleate, or a mixture of these esters; polyesters of molecular weight between 1000 and 3000 and resulting from the condensation between a poly (isobutenyl) succinic acid or its anhydride, such as HYPERMER ™ 2296, or the mixture sold under the brand name SIMALINE ™ IE 501 A, polyglycol polyhydroxystearates of formula (IX):
    formula (IX) in which y 2 represents an integer greater than or equal to 2 and less than or equal to 50, Z 4 represents the hydrogen atom, the methyl radical, or the ethyl radical, Z 3 represents a radical of formula (X):
    formula (X) in which y ' 2 represents an integer greater than or equal to 0 and less than or equal to 10, more particularly greater than or equal to 1 and less than or equal to 10 and Z' 3 represents a radical of formula (X) as defined above, with Z 3 'identical to or different from Z 3 , or the hydrogen atom.
    As an example of an emulsifying surfactant of the water-in-oil type of formula (IX) which can be used to prepare the emulsifying system (Si), there is PEG-30 dipolyhydroxystearate marketed under the name SIMALINE ™ WO, or else mixtures comprising PEG-30 dipolyhydroxystearate and marketed under the names SIMALINE ™ IE 201 A and SIMALINE ™ IE 201 B, or alternatively the mixture comprising Trimethylolpropane-30 tripolyhydroxystearate marketed under the name SIMALINE ™ IE 301 B.
    In said self-reversible reverse latex which is the subject of the present invention, the emulsifier system (S 2 ) of the oil-in-water type consists either of the single composition (C e ) or of a mixture of said composition (C e ) with one or more other emulsifying surfactants, provided that the resulting emulsifying system (S 2 ) has an HLB value high enough to induce the formation of oil-ineau-type emulsions.
    According to another more particular aspect of the present invention, said self-reversible reverse latex as defined above is characterized in that in formula (I), n represents an integer greater than or equal to one and less than or equal to ten, and in that in formula (II), p, identical or different from n, represents an integer greater than or equal to one and less than or equal to ten, and the group Ri- (C = O) - is chosen from octanoyl, decanoyl, ω-undecylenoyl, dodecanoyl, tetradecanoyl, hexadecanoyl, octadecanoyl, 9-octadecenoyl or 9,12-octadecadienoyl radicals.
    According to another even more particular aspect of the present invention, in said formulas (I) and (II) as defined above, n is equal to 10, p is equal to 10, and the group Ri- (C = O) - is the dodecanoyl radical; n is 6, p is 10, and the group Ri- (C = O) - is the dodecanoyl radical; n is equal to 6, p is equal to 6, and the group Ri- (C = O) - is the dodecanoyl radical or n is equal to 1, p is equal to 10, and the group Ri- (C = O) - is the dodecanoyl radical.
    According to another more particular aspect of the present invention, said self-reversible reverse latex as defined above is characterized in that in said oil-in-water type emulsifier system (S 2 ) said composition (C e ) as defined previously, consists of, for 100% of its mass:
    ei) - From 10% by mass to 60% by mass of at least one compound of formula (I) as defined above and e 2 ) - From 40% by mass to 90% by mass of at least one compound of formula (II) as defined above.
    The term “reducing sugar” denotes in formula (III) as defined above, the saccharide derivatives which do not have, in their glycosidic binding structures established between an anomeric carbon and the oxygen of an acetal group as defined. in the reference work: Biochemistry, Daniel Voet / Judith G. Voet, p. 250, John Wyley & Sons, 1990. The oligomeric structure (G) x can occur in any form of isomerism, whether it is optical isomerism, geometric isomerism or position isomerism; it can also represent a mixture of isomers.
    According to another more particular aspect of the present invention, in composition (C e ) as defined above, G represents, in formula (III) as defined above, the remainder of a reducing sugar chosen from the remnants of glucose , dextrose, sucrose, fructose, idose, gulose, galactose, maltose, isomaltose, maltotriose, lactose, cellobiose, mannose, ribose, xylose, arabinose, lyxose, allose, altrose, dextran or tallose. Said residue G even more particularly represents in formula (III) as defined above, a reducing sugar chosen from the residues of glucose, xylose and arabinose.
    By formula (III):
    HO-CH 2 - (CHOH) q -CH 2 -O- (G) r -H, representing the composition (Cn), it is signified that this composition (Cn) essentially consists of a mixture of compounds represented by the formulas (llh ), (lll 2 ), (lll 3 ), (lll 4 ) and (III5):
    HO-CH 2 - (CHOH) q -CH 2 -O- (G) iH (llh),
    HO-CH 2 - (CHOH) q -CH 2 -O- (G) 2 -H (lll 2 ),
    HO-CH 2 - (CHOH) q -CH 2 -O- (G) 3 -H (lll 3 ),
    HO-CH 2 - (CHOH) q -CH 2 -O- (G) 4 -H (lll 4 ),
    HO-CH 2 - (CHOH) q -CH 2 -O- (G) 5 -H (lll 5 ), in the respective molar proportions ai, a 2 , a 3 , a 4 and a 5 , such that the sum ai + a 2 + a 3 + a 4 + a 5 is equal to 1 and that the sum ai + 2a 2 + 3a 3 + 4a 4 + 5a 5 is equal to r.
    By essentially, it is indicated in the above definition, that the presence of one or more compounds of formula (III w ) with w greater than 5 is not excluded within the composition (Cn), but that if presence there are, it is in minimal proportions which do not entail any substantial modification of the properties of said composition (C11). In formula (III) as defined above, the group HO-CH 2 - (CHOH) q -CH 2 -O- is linked to (G) r by the anomeric carbon of the saccharide residue, so as to form a acetal function.
    According to a more particular aspect of the present invention, in the formula (III) representing the composition (Cn) as defined above, r represents a decimal number greater than or equal to 1.05 and less than or equal to 3, more particularly greater than or equal to 1.15 and less than or equal to 2.5.
    According to a more particular aspect of the present invention, said self-reversible reverse latex as defined above is characterized in that in formula (III) as defined above, q is equal to one, G represents the remainder of the glucose and r represents a decimal number greater than or equal to 1.05 and less than or equal to 2.5.
    According to another particular aspect of the present invention, said self-reversible reverse latex as defined above is characterized in that in said oil-in-water type emulsifier system (S 2 ), said composition (C e ) as defined above consists in, for 100% of its mass:
    ei) - From 5% by mass to 15% by mass of at least one compound of formula (I) as defined above, e 2 ) - From 60% by mass to 80% by mass of at least one compound of formula (II) as defined above, and e 3 ) - From 5% to 15% by mass of at least one composition (Cn) represented by the formula (III) as defined above.
    According to another particular aspect of the present invention, said emulsifier system (S 2 ) of oil-in-water type comprises for 100% of its mass, at least 75% by mass of said composition (C e ) as defined above.
    According to a very particular aspect, said reverse latex as defined above is characterized in that said emulsifying system of oil-in-water type (S 2 ) is said composition (C e ) as defined above.
    Said self-reversible reverse latex which is the subject of the present invention is prepared by the implementation of a process known as “reverse emulsion polymerization”, well known to those skilled in the art, and which comprises the following steps:
    - A step a) of preparation of an aqueous phase comprising water, the water-soluble monomers and optionally the crosslinking monomer (AR), as well as additives commonly used such as, for example, sequestering agents such as ethylenediaminetetracetic (EDTA) in its sodium form, or the pentasodium salt of penta acetic acid of diethylenetramine (sold under the brand name Versenex ™ 80);
    - A step b) of mixing the oily phase (H) with the water-in-oil type emulsifier system (Si);
    - A step c) of mixing the aqueous phase and the oily phase, prepared during the previous steps, and emulsification using a rotorstator type mobile;
    - A step d) of nitrogen inerting;
    - A step e) of initiation of the polymerization reaction by introduction into the emulsion formed in c), of a free radical initiator and possibly a co-initiator; then we let it unfold,
    - A step f) of introducing the emulsifier system (S 2 ) of the oil-in-water type as defined above at a temperature less than or equal to 50 ° C.
    According to a particular aspect of the process as defined above, the polymerization reaction of step e) is initiated by an oxido-reducing couple generating hydrogen sulfite ions (HSO 3 ), such as the cumene hydroperoxide couple of sodium metabisulfite. (Na 2 S 2 O 5 ) or the cumene hydroperoxide-thionyl chloride couple (SOCI 2 ) at a temperature less than or equal to 10 ° C, siderée accompanied by a co-initiator of polymerization such as for example razo- bis (isobutyronitrile) then conducted either in an almost adiabatic manner up to a temperature greater than or equal to 50 ° C., or by controlling the temperature.
    According to another particular aspect of the process as defined above, the reaction medium from step e) is concentrated by distillation, before the implementation of step f).
    According to another particular aspect of the process as defined above, the reaction medium resulting from step e) or from step f) undergoes a spray drying step in a suitable installation.
    According to another particular aspect of the process as defined above, the aqueous phase prepared in step a) can comprise chain reducing agents, intended to reduce the length of the polymer chains formed and to increase the rate of connection to the polymer, so as to modify the rheological properties.
    Among the chain reducing agents suitable for the process as defined above, there are methanol, isopropanol, butylene glycol, 2-mercapto ethanol, thioglycolic acid, formic acid or its salts.
    The subject of the invention is also a composition (C e ) which comprises per 100% of its mass:
    ei) - From 10% by mass to 60% by mass, more particularly from 15% by mass to 60% by mass and even more particularly from 15% by mass to 50% by mass, of at least one compound of formula (I) :
    HO- [CH 2 -CH (OH) -CH 2 -O] n -H (I) wherein n represents an integer greater than or equal to one and less than or equal to fifteen;
    e 2 ) - From 40% by mass to 90% by mass, more particularly from 40% by mass to 85% by mass and even more particularly from 50% by mass to 85% by mass, of at least one compound of formula (II):
    Ri- (C = O) - [O-CH 2 -CH (OH) -CH 2 ] p -OH (II), in which p, different or identical to n, represents an integer greater than or equal to one and less or equal to fifteen and the group Ri- (C = O) - represents a saturated or unsaturated, linear or branched aliphatic radical, comprising from six to twenty-two carbon atoms, and optionally e 3 ) - Up to 30% by mass 0% by mass to 30% by mass, more particularly from 0% by mass to 25% by mass and more particularly from 0% by mass to 20% by mass of at least one composition (Cn) represented by the formula (III): HO- [CH 2 -CHOH-CH 2 -O-] q - (G) r -H (III), formula (III) in which q, different or identical to n, represents an integer greater than or equal to one and less than or equal to 3, G represents the remainder of a reducing sugar and r represents a decimal number greater than or equal to 1.05 and less than or equal to 5.00, said composition (Cn) consisting of a mixture of the compounds of formulas (l lh), (lll 2 ), (Ilia), (lll 4 ) and (III5):
    HO- [CH 2 -CHOH-CH 2 -O-] q -O- (G) iH (llh),
    HO- [CH 2 -CHOH-CH 2 -O-] q -O- (G) 2 -H (lll 2 ),
    HO- [CH 2 -CHOH-CH 2 -O-] q -O- (G) 3 -H (lll 3 ),
    HO- [CH 2 -CHOH-CH 2 -O-] q -O- (G) 4 -H (lll 4 ),
    HO- [CH 2 -CHOH-CH 2 -O-] q -O- (G) 5 -H (lll 5 ), in molar proportions as said compounds of formulas (llh), (lll 2 ), (llh) , (IlI4) and (lll 5 ) respectively equal to a b a 2 , a 3 , a 4 and a 5 , such that the sum ai + a 2 + a 3 + a4 + a 5 is equal to one, and that the sum ai + 2a 2 + 3a 3 + 4a 4 + 5a 5 is equal to r;
    the sum of the mass proportions of compounds according to ei), e 2 ) and e 3 ) being equal to 100% by mass.
    According to a particular aspect, the composition (Ce) as defined above is characterized in that in the formula (I) n represents an integer greater than or equal to one and less than or equal to ten and in the formula (II) p, different from n, represents an integer greater than or equal to one and less than or equal to ten.
    According to this particular aspect, the composition (Ce) as defined above is more particularly characterized in that in the formula (I) as defined above, n is equal to 1 or to 6 and in the formula (II) p is equal to 6 or 10.
    According to this particular aspect, the composition (C e ) as defined above is also characterized in that in the formulas (I) and (II) as defined above, n and p are identical and each represent an integer greater than or equal to 1 and less than or equal to 10 and in particular greater than or equal to 4 and less than or equal to 8.
    According to this particular aspect, the composition (Ce) as defined above is more particularly characterized in that in the formulas (I) and (II) as defined, n and p are equal to 6.
    According to another particular aspect of the present invention, in formula (II) as defined above, the group Ri- (C = O) - is chosen from the elements of the group consisting of the octanoyl, decanoyl, ω-undecylenoyl radicals, dodecanoyl, tetradecanoyl, hexadecanoyl, octadecanoyl, 9-octadecenoyl or 9,12-octadecadienoyl; it is more particularly the dodecanoyl radical.
    A further subject of the invention is also the composition (C e ) as defined above, characterized in that it consists, for 100% of its mass:
    ei) - From 10% by mass to 60% by mass of at least one compound of formula (I) as defined above and e 2 ) - From 40% by mass to 90% by mass of at least one compound of formula (II) as defined above.
    A further subject of the invention is also the composition (C e ) as defined above, characterized in that in formula (III) as defined above, q is equal to one, G represents the remainder of the glucose and r represents a decimal number greater than or equal to 1.05 and less than or equal to 2.5.
    According to another particular aspect of the present invention, the composition (C e ) as defined above is characterized in that it consists, for 100% of its mass:
    ei) - From 5% by mass to 15% by mass of at least one compound of formula (I) as defined above, e 2 ) - From 60% by mass to 80% by mass of at least one compound of formula (II) as defined above, and e 3 ) - From 5% to 15% by mass of at least one composition (Cn) represented by the formula (III) as defined above.
    The term “reducing sugar” denotes, in formula (III), the saccharide derivatives as defined above and G represents, in the formula (III) as defined above, the remainder of a reducing sugar chosen from the residues of glucose, dextrose, sucrose, fructose, idose, gulose, galactose, maltose, isomaltose, maltotriose, lactose, cellobiose, mannose, ribose, xylose, arabinose, lyxose, allose, altrose, dextran or tallose, and more particularly among the residues of glucose, xylose and arabinose.
    The formula (III) representing the composition (Cn), consists of a mixture of compounds represented by the formulas (llh), (lll 2 ), (llb), (III4) and (III5) as defined above. According to a more particular aspect of the present invention, in the formula (III) representing the composition (Cn) as defined above, r represents a decimal number greater than or equal to 1.05 and less than or equal to 3, more particularly greater than or equal to 1.15 and less than or equal to 2.5.
    According to a more particular aspect, the invention relates to a composition (Ce) as defined above, for which, in formula (III), q is equal to one, G represents the remainder of the glucose and r represents a decimal number greater than or equal to 1.05 and less than or equal to 2.5.
    According to another particular aspect, the invention relates to a composition (Ce) as defined above, for which in formula (I), n represents an integer greater than or equal to one and less than or equal to ten, in the formula (II) p, identical or different from n, represents an integer greater than or equal to one and less than or equal to ten and the group Ri- (C = O) - is chosen from octanoyl, decanoyl, ω-undecylenoyl radicals , dodecanoyl, tetradecanoyl, hexadecanoyl, octadecanoyl, 9-octadecenoyl or 9,12-octadecadienoyl, and in formula (III), q is equal to one, G represents the rest of the glucose and r represents a decimal number greater than or equal to 1 , 05 and less than or equal to 2.5.
    According to a very particular aspect, the subject of the invention is a composition (Ce) as defined above, for which in the formula (I) n is equal to one, in the formula (II) p is equal to 10 and the group Ri- (C = O) - is the dodecanoyl radical and in formula (III), q is equal to one, G represents the rest of the glucose and r represents a decimal number greater than or equal to 1.05 and less than or equal to 2.5.
    The composition (Cn) optionally included in the composition (Ce) is prepared according to a process comprising the following steps:
    - A step A) of reaction, in the desired proportions, of a reducing sugar of formula (XI) or a mixture of reducing sugars of formula (XI):
    HO-G-H (XI) in which G represents the remainder of a reducing sugar, with a molar excess of a compound of formula (XII) or of a mixture of compounds of formula (XII):
    HO- [CH 2 -CHOH-CH 2 -O-] q H (XII), formula (XII) for which q is as defined above for formula (III), to form a mixture of compounds of formula (III) as defined above and an excess of said compound of formula (XII).
    Step (A) of the process as defined above, can be supplemented, if necessary or if desired, by subsequent neutralization operations, for example with soda or potash, and / or filtration, and / or discoloration, and / or elimination of the residual polyol, for example by selective extraction using a suitable solvent medium.
    Stage A) is generally carried out in a reactor in the presence of an acidic catalytic system, by controlling the stoichiometric ratio between the two reactants, and more particularly by introducing a molar excess of the mixture of alcohols of formula (II) , with mechanical stirring under predetermined temperature and partial vacuum conditions, for example at a temperature between 70 ° C and 130 ° C and under a partial vacuum between 300mbar (3.10 4 Pa) and 20mbar (2.10 3 Pa). The expression “acid catalytic system” denotes strong acids such as sulfuric acid, hydrochloric acid, phosphoric acid, nitric acid, hypophosphorous acid, methanesulfonic acid, para-toluene sulfonic acid, l trifluoromethanesulfonic acid, or ion exchange resins.
    The subject of the invention is also the use of said self-reversible reverse latex as defined above, as a thickening and / or emulsifying and / or stabilizing agent of a topical cosmetic or pharmaceutical composition.
    According to another particular aspect, said use consists in stabilizing an emulsion of oil-in-water type, or of water-in-oil type, by imparting a homogeneous appearance to said emulsion during storage under different conditions, and more particularly at 25. ° C for a duration at least equal to one month, and more particularly at 4 ° C for a duration at least equal to one month, and more particularly at 45 ° C for a duration at least equal to one month.
    According to another particular aspect, said use consists in stabilizing solid particles in topical cosmetic, dermopharmaceutical or pharmaceutical compositions. These solid particles to be suspended can have different geometries, regular or irregular, and be in the form of pearls, beads, rods, flakes, lamellae or polyhedra. These solid particles are characterized by an apparent average diameter of between one micrometer and five millimeters, more particularly between ten micrometers and one millimeter.
    Among the solid particles which can be suspended and stabilized by the self-reversible reverse latex as defined above in topical cosmetic, dermopharmaceutical or pharmaceutical compositions, there are micas, iron oxide, titanium oxide. , zinc oxide, aluminum oxide, talc, silica, kaolin, clays, boron nitride, calcium carbonate, magnesium carbonate, magnesium hydrogen carbonate, colored pigments inorganic, polyamides such as nylon-6, polyethylenes, polypropylenes, polystyrenes, polyesters, acrylic or methacrylic polymers such as polymethylmethacrylates, polytetrafluoroethylene, crystalline or microcrystalline waxes, porous spheres, selenium sulphide, zinc pyrithione, starches, alginates, plant fibers, Loofah particles, sponge particles.
    The subject of the invention is also a topical cosmetic composition (F) or a topical pharmaceutical composition (G), characterized in that it comprises, as thickening agent, for 100% of its total mass between 0.1% and 10% by mass of said self-reversible reverse latex as defined above.
    The topical expression used in the definitions of said compositions (F) and (G), signifies that they are used by application to the skin, hair, scalp or mucous membranes, whether '' a direct application in the case of a cosmetic, dermocosmetic, dermopharmaceutical or pharmaceutical preparation or an indirect application for example in the case of a body care product in the form of a textile or paper wipe or sanitary products intended to be in contact with the skin or mucous membranes.
    Said compositions (F) and (G) are generally in the form of an aqueous or hydro-alcoholic or hydro-glycolic solution, in the form of a suspension, an emulsion, a microemulsion or a nano -emulsion, whether of the water-in-oil, oil-in-water, water-in-oil-in-water or oil-in-water-in-oil type.
    Said compositions (F) and (G), can be packaged in a bottle, in a device of the pump bottle type, in pressurized form in an aerosol device, in a device provided with an openwork wall such as a grid or in a device provided a ball applicator (called roll-on).
    In general, said compositions (F) and (G) also comprise excipients and or active ingredients usually used in the field of formulations for topical use, in particular cosmetic, dermocosmetic, pharmaceutical or dermopharmaceuticals, such as thickening surfactants and / or gelling agents, stabilizers, film-forming compounds, hydrotropic agents, plasticizing agents, emulsifying and co-emulsifying agents, opacifying agents, pearlescent agents, superfatting agents, sequestrants, chelating agents, antioxidants, perfumes, preservatives, conditioning agents, bleaching agents intended for bleaching hair and skin, active principles intended to provide a treating action with respect to the skin or hair, sun filters, mineral fillers or pigments, particles providing a visual effect or intended for the encapsulation of Active ingredients, exfoliating particles, texture agents.
    As examples of foaming and / or detergent surfactants which can be combined with said self-reversible reverse latex as defined above in said compositions (F) and (G), there are cationic foaming surfactants and / or anionic detergents. , amphoteric or non-ionic.
    Among the anionic foaming and / or detergent surfactants which can be combined with said self-reversible reverse latex as defined above in said compositions (F) and (G), there are the salts of alkali metals, alkali metal- earthy, ammonium, amines, or amino alcohols of alkyl ether sulfates, alkyl sulfates, alkylamidoether sulfates, alkylaryl polyethersulfates, monoglycerides sulfates, alpha olefins sulfonates, paraffins sulfonates, alkyl phosphates , alkyl ether phosphates, alkyl sulfonates, alkylamide sulfonates, alkylaryl sulfonates, alkyl carboxylates, alkyl sulfosuccinates, alkyl ether sulfosuccinates, alkylamide sulfosuccinates, alkyl sulfoacetates, alkyl sarcosinates , acyl isethionates, N-acyl taurates, acyl lactylates, N-acylated derivatives of amino acids, N-acylated derivatives of peptides, N-acylated derivatives of proteins, N-acylated derivatives of acid are bold.
    Among the foaming amphoteric surfactants and / or detergents which can be associated with said self-reversible reverse latex as defined above in said compositions (F) and (G), there are alkylbetaines, alkylamidobetaines, sultaines, alkylamidoalkylsulfobetaines, imidazoline derivatives, phosphobetaines, amphopolyacetates and amphopropionates.
    Among the foaming cationic surfactants and / or detergents which can be combined with said self-reversible reverse latex as defined above in said compositions (F) and (G), there are in particular quaternary ammonium derivatives.
    Among the foaming nonionic surfactants and / or detergents which can be combined with said self-reversible reverse latex as defined above in said compositions (F) and (G), there are more particularly alkylpolyglycosides comprising an aliphatic radical, linear or branched, saturated or unsaturated, and having from 8 to 16 carbon atoms, such as octyl polyglucoside, decyl polyglucoside, undecylenyl polyglucoside, dodecyl polyglucoside, tetradecyl polyglucoside, hexadecyl polyglucoside, 1-12 dodecanediyl polyglucoside; ethoxylated hydrogenated castor oil derivatives such as the product sold under the name INCI "Peg-40 hydrogenated castor oil"; polysorbates such as Polysorbate 20, Polysorbate 40, Polysorbate 60, Polysorbate 70, Polysorbate 80, Polysorbate 85; copra amides; N-alkylamines.
    As examples of thickening and / or gelling surfactants which can be combined with said self-reversible reverse latex as defined above in said compositions (F) and (G), there are fatty esters of optionally alkoxylated alkylpolyglycosides, such as ethoxylated methylpolyglucoside esters such as PEG 120 methyl glucose trioleate and PEG 120 methyl glucose dioleate sold respectively under the names GLUCAMATE ™ LT and GLUMATE ™ DOE120; alkoxylated fatty esters such as PEG 150 pentaerythrytyl tetrastearate marketed under the name CROTHIX ™ DS53, PEG 55 propylene glycol oleate marketed under the name ANTIL ™ 141; fatty chain polyalkylene glycol carbamates such as PPG-14 laureth isophoryl dicarbamate sold under the name ELFACOS ™ T211, PPG-14 palmeth-60 hexyl dicarbamate sold under the name ELFACOS ™ GT2125.
    As examples of thickening and / or gelling agents which can be combined with said self-reversible reverse latex as defined above in said compositions (F) and (G), there are the copolymers of AMPS and of alkyl acrylates, the carbon chain of which comprises between four and thirty carbon atoms and more particularly between ten and thirty carbon atoms, the linear, branched or crosslinked terpolymer of at least one monomer having a strong, free, partially salified acid function or totally salified, with at least one neutral monomer, and at least one monomer of formula (XIII):
    CH 2 = C (R ' 3 ) -C (= O) - [CH 2 -CH 2 -O] n'-R' 4 (XIII) in which R ' 3 represents a hydrogen atom or a methyl radical, R'4 represents a linear or branched alkyl radical containing from eight to thirty carbon atoms and ri represents a number greater than or equal to one and less than or equal to fifty.
    As examples of thickening and / or gelling agents which can be combined with said self-reversible reverse latex as defined above in said compositions (F) and (G), there are the polysaccharides consisting solely of oses, such as glucans or homopolymers of glucose, glucomannoglucans, xyloglycans, galactomannans whose degree of substitution (DS) of D-galactose units on the main chain of D-mannose is between 0 and 1, and more particularly between 1 and 0.25, like galactomannans from cassia gum (DS = 1/5), locust bean gum (DS = 1/4), tara gum (DS = 1/3), gum guar (DS = 1/2), fenugreek gum (DS = 1).
    As examples of thickening and / or gelling agents which can be combined with said self-reversible reverse latex as defined above in said compositions (F) and (G), there are the polysaccharides consisting of derivatives of oses, such as sulfated galactans and more particularly carrageenans and agar, uronanes and more particularly algines, alginates and pectins, heteropolymers of oses and uronic acids and more particularly xanthan gum, gellan gum, exudate of arabic gum and karaya gum, glucosaminoglycans.
    As examples of thickening and / or gelling agents which can be combined with said self-reversible reverse latex as defined above in said compositions (F) and (G), there is cellulose, cellulose derivatives such as methyl cellulose, ethyl cellulose, hydroxypropyl cellulose, silicates, starch, hydrophilic starch derivatives, polyurethanes.
    As examples of stabilizing agents which can be combined with said self-reversible reverse latex as defined above in said compositions (F) and (G), there are microcrystalline waxes, and more particularly ozokerite, the salts minerals such as sodium chloride or magnesium chloride, silicone polymers such as polysiloxane polyalkyl polyether copolymers.
    As examples of solvents which can be combined with said self-reversible reverse latex as defined above in said compositions (F) and (G), there are water, organic solvents such as glycerol, diglycerol, oligomers of glycerol, ethylene glycol, propylene glycol, butylene glycol, 1,3-propanediol, 1,2-propanediol, hexylene glycol, diethylene glycol, xylitol, erythritol, sorbitol, water-soluble alcohols such as ethanol, isopropanol or butanol, mixtures of water and of said organic solvents.
    As examples of thermal or mineral waters which can be associated with said self-reversible reverse latex as defined above in said compositions (F) and (G), there are thermal or mineral waters having at least mineralization. minus 300 mg / l, in particular Avene water, Vittel water, Vichy basin water, Uriage water, Roche Posay water, Bourboule water, water from Enghien-les-bains, water from Saint-Gervais-les bains, water from Néris-les-bains, water from Allevard-les-bains, water from Digne, l water from Maizieres, water from Neyrac-les-bains, water from Lons le Saunier, water from Rochefort, water from Saint Christau, water from Fumades and water from Tercis-les- baths.
    As examples of hydrotropic agents which can be combined with said self-reversible reverse latex as defined above, in said compositions (F) and (G), there are the xylenes sulfonates, the cumenes sulfonates, the hexylpolyglucoside, 2-ethylhexylpolyglucoside, n-heptylpolyglucoside.
    As examples of emulsifying surfactants which can be combined with said self-reversible reverse latex as defined above in said compositions (F) and (G), there are nonionic surfactants, anionic surfactants, cationic surfactants .
    As examples of nonionic emulsifying surfactants which can be combined with said self-reversible reverse latex as defined above in said compositions (F) and (G), there are the esters of fatty acids and of sorbitol, such as the products sold under the names MONTANE ™ 40, MONTANE ™ 60, MONTANE ™ 70, MONTANE ™ 80 and MONTANE ™ 85; compositions comprising glycerol stearate and ethoxylated stearic acid between 5 moles and 150 moles of ethylene oxide, such as the composition comprising ethoxylated stearic acid with 135 moles of ethylene oxide and glycerol stearate sold under the name SIMULSOL ™ 165; mannitan esters; ethoxylated mannitan esters; sucrose esters; methylglucoside esters; alkylpolyglycosides comprising an aliphatic radical, linear or branched, saturated or unsaturated, and comprising from 14 to 36 carbon atoms, such as tetradecyl polyglucoside, hexadecyl polyglucoside, octadecyl polyglucoside, hexadecyl polyxyloside, octadecyl polyxyloside, eicosyl polyglucoside, dodecosyl polyglucoside, 2-octyldodecyl polyxyloside, 12-hydroxystearyl polyglucoside; the compositions of linear or branched fatty alcohols, saturated or unsaturated, and comprising from 14 to 36 carbon atoms, and of alkylpolyglycosides as described above, for example the compositions sold under the names MONTANOV ™ 68, MONTANOV ™ 14, MONTANOV ™ 82, MONTANOV ™ 202, MONTANOV ™ S, MONTANOV ™ WO18, MONTANOV ™ L, FLUIDANOV ™ 20X and EASYNOV ™.
    As examples of anionic surfactants which can be combined with said self-reversible reverse latex as defined above in said compositions (F) and (G), there are glyceryl stearate citrate, cetearyl sulphate, soaps such as stearate sodium or triethanolammonium stearate, N-acylated derivatives of salified amino acids, for example stearoyl glutamate.
    As examples of cationic emulsifying surfactants which can be combined with said self-reversible reverse latex as defined above in said compositions (F) and (G), there are the aminoxides, quaternium-82 and the surfactants described in patent application WO96 / 00719 and mainly those in which the fatty chain comprises at least 16 carbon atoms.
    As examples of opacifying and / or pearlescent agents which can be combined with said self-reversible reverse latex as defined above in said compositions (F) and (G), there are sodium palmitate, sodium stearate. , sodium hydroxystearate, magnesium palmitate, magnesium stearate, magnesium hydroxystearate, ethylene glycol monostearate, ethylene glycol distearate, polyethylene glycol monostearate, polyethylene glycol distearate, fatty alcohols having from 12 to 22 carbon atoms.
    As examples of texturing agents which can be combined with said self-reversible reverse latex as defined above in said compositions (F) and (G), there are N-acylated derivatives of amino acids, such as lauroyl lysine marketed under the name AMINOHOPE ™ LL, octenyl starch succinate marketed under the name DRYFLO ™, myristyl polyglucoside marketed under the name MONTANOV ™ 14, cellulose fibers, cotton fibers, chitosan fibers , talc, sericite, mica
    As examples of deodorant agents which can be combined with said self-reversible reverse latex as defined above in said compositions (F) and (G), there are alkali silicates, zinc salts such as zinc sulfate, zinc gluconate, zinc chloride, zinc lactate; quaternary ammonium salts such as cetyltrimethylammonium salts, cetylpyridinium salts; glycerol derivatives such as glycerol caprate, glycerol caprylate, polyglycerol caprate; 1,2 decanediol; 1,3 propanediol; salicylic acid; sodium bicarbonate; cyclodextrins; metallic zeolites; TRICLOSAN ™; aluminum hydrobromide, aluminum hydrochlorides, aluminum chloride, aluminum sulfate, aluminum and zirconium hydrochlorides, aluminum and zirconium hydrochloride, aluminum and zirconium tetrachloride , aluminum and zirconium pentachlorhydrate, aluminum and zirconium octochlorhydrate, aluminum sulfate, sodium and aluminum lactate, aluminum hydrochloride and glycol complexes, such as aluminum hydrochloride and propylene glycol, aluminum dihydrochloride and propylene glycol complex, aluminum sesquichlorohydrate and propylene glycol complex, aluminum hydrochloride and polyethylene glycol complex, dihydrochloride complex aluminum and polyethylene glycol, the complex of aluminum sesquichlorohydrate and polyethylene glycol.
    As examples of oils that can be combined with said self-reversible reverse latex as defined above in said compositions (F) and (G), there are mineral oils such as paraffin oil, oil petrolatum, isoparaffins or white mineral oils; oils of animal origin, such as squalene or squalane; vegetable oils, such as phytosqualane, sweet almond oil, coconut oil, castor oil, jojoba oil, olive oil, rapeseed oil, peanut oil, sunflower oil, wheat germ oil, corn germ oil, soybean oil, cottonseed oil, alfalfa oil, poppy oil , pumpkin oil, evening primrose oil, millet oil, barley oil, rye oil, safflower oil, bancoulier oil, passionflower oil , hazelnut oil, palm oil, shea butter, apricot kernel oil, calophyllum oil, sysymbrium oil, avocado oil, calendula, oils from flowers or vegetables ethoxylated vegetable oils; synthetic oils such as fatty acid esters such as butyl myristate, propyl myristate, isopropyl myristate, cetyl myristate, isopropyl palmitate, octyl palmitate, butyl stearate, hexadecyl stearate, isopropyl stearate, octyl stearate, isocetyl stearate, dodecyl oleate, hexyl laurate, propylene glycol dicaprylate, esters derived from lanolic acid, such as isopropyl lanolate, isocetyl lanolate, monoglycerides, diglycerides and triglycerides of fatty acids such as glycerol triheptanoate, alkylbenzoates, hydrogenated oils, poly (alpha-olefins), polyolefins such as poly (isobutane ), synthetic isoalkanes such as isohexadecane, isododecane, perfluorinated oils; silicone oils such as dimethylpolysiloxanes, methylphenylpolysiloxanes, silicones modified by amines, silicones modified by fatty acids, silicones modified by alcohols, silicones modified by alcohols and fatty acids, silicones modified by polyether groups, modified epoxy silicones, silicones modified by fluorinated groups, cyclic silicones and silicones modified by alkyl groups. By "oils" is meant in the present application the compounds and / or mixtures of compounds insoluble in water, having a liquid appearance at a temperature of 25 ° C.
    As examples of waxes which can be combined with said self-reversible reverse latex as defined above in said compositions (F) and (G), there are beeswax, carnauba wax, candelilla wax , ouricoury wax, Japanese wax, cork fiber wax, sugar cane wax, paraffin waxes, lignite waxes, microcrystalline waxes, lanolin wax; ozokerite; polyethylene wax; silicone waxes; vegetable waxes; fatty alcohols and fatty acids solid at room temperature; solid glycerides at room temperature. By "waxes" is meant in the present application the compounds and / or mixtures of compounds insoluble in water, having a solid appearance at a temperature greater than or equal to 45 ° C.
    As examples of active principles which can be combined with said self-reversible reverse latex as defined above in said compositions (F) and (G), there are vitamins and their derivatives, in particular their esters, such as retinol. (vitamin A) and its esters (retinyl palmitate for example), ascorbic acid (vitamin C) and its esters, sugar derivatives of ascorbic acid (like ascorbyl glucoside), tocopherol (vitamin E) and its esters (such as tocopherol acetate), vitamins B3 or B10 (niacinamide and its derivatives); compounds showing a lightening or depigmenting action on the skin such as ω-undecelynoyl phenylalanine sold under the name SEPIWHITE ™ MSH, SEPICALM ™ VG, the mono ester and / or glycerol diester of ω-undecelynoyl phenylalanine, ω- undecelynoyl dipeptides, arbutin, kojic acid, hydroquinone; compounds showing a soothing action, in particular SEPICALM ™ S, allantoin and bisabolol; anti-inflammatory agents; compounds showing a hydrating action such as urea, hydroxyureas, glycerol, polyglycerols, glycerolglucoside, diglycerolglucoside, polyglycerylglucosides, xylitylplucoside; plant extracts rich in polyphenols such as grape extracts, pine extracts, wine extracts, olive extracts; compounds showing a slimming or lipolytic action such as caffeine or its derivatives, ADIPOSLIM ™, ADIPOLESS ™, fucoxanthin; N-acylated proteins; N-acylated peptides such as MATRIXIL ™; N-acylated amino acids; partial hydrolysates of N-acylated proteins; amino acids; peptides; total protein hydrolysates; soy extracts, for example Raffermine ™; wheat extracts, for example TENSINE ™ or GLIADINE ™; plant extracts, such as plant extracts rich in tannins, plant extracts rich in isoflavones or plant extracts rich in terpenes; extracts of freshwater or marine algae; extracts of marine plants; marine extracts in general such as corals; essential waxes; bacterial extracts; ceramides; phospholipids; compounds showing an antimicrobial action or a purifying action, such as LIPACIDE ™ C8G, LIPACIDE ™ UG, SEPICONTROL ™ A5; OCTOPIROX ™ or SENSIVA ™ SC50; compounds showing an energizing or stimulating property such as PHYSIOGENYL ™, panthenol and its derivatives such as SEPICAP ™ MP; anti-aging active ingredients such as SEPILIFT ™ DPHP, LIPACIDE ™ PVB, SEPIVINOL ™, SEPIVITAL ™, MANOLIVA ™, PHYTO-AGE ™, TIMECODE ™; SURVICODE ™; anti-aging photo active ingredients; protective agents for the integrity of the dermo-epidermal junction; active ingredients increasing the synthesis of components of the extracellular matrix such as collagen, elastins, glycosaminoglycans; active agents favorably acting on chemical cellular communication such as cytokines or physical ones such as integrins; active ingredients creating a feeling of "warming" on the skin such as activators of the cutaneous microcirculation (like derivatives of nicotinic acid) or products creating a feeling of "freshness" on the skin (like menthol and derivatives); active ingredients improving skin microcirculation, for example veinotonics; draining active ingredients; decongestant active ingredients such as extracts of ginko biloba, ivy, horse chestnut, bamboo, ruscus, small holly, centalla asiatica, fucus, rosemary, willow; agents for tanning or browning the skin, for example ladihydroxyacetone (DHA), erythrulose, mesotartaric aldehyde, glutaraldehyde, glyceraldehyde, alloxane, ninhydrin, plant extracts for example red wood extracts of the genus Pterocarpus and of the genus Baphia such as Pteropcarpus santalinus, Pterocarpus osun, Pterocarpus soyauxii, Pterocarpus erinaceus, Pterocarpus indicus or Baphia nitida such as those described in European patent application EP 0 971 683; agents known for their facilitating and / or accelerating action on the tanning and / or browning of human skin, and / or for their coloring action on human skin, for example caratenoids (and more particularly beta carotene and gamma carotene), the product marketed under the brand name "Carrot oil" (INCI name: Daucus Carota, helianthus annuus Sunflower oil) by the company Provital, which contains carotenoids, vitamin E and vitamin K ; tyrosine and / or its derivatives, known for their effect on the acceleration of tanning of human skin in association with exposure to ultraviolet radiation, for example the product marketed under the brand name "SunTan
    Accelerator ™ "by the company Provital which contains tyrosine and riboflavins (vitamin B), the tyrosine and tyrosinase complex sold under the brand name" Zymo Tan Complex "by the company Zymo Line, the product sold under the brand name MelanoBronze ™ (INCI name: Acetyl Tyrosine, Monk's pepper extract (Vitex Agnus-castus)) by the company Mibelle which contains acetyl tyrosine, product marketed under the brand name Unipertan VEG-24/242/2002 ( INCI name: butylene glycol and Acetyl Tyrosine and hydrolyzed vegetable protein and Adenosine triphosphate) by the company UNIPEX, the product marketed under the brand name "TryExcell ™" (INCI name: Oleoyl Tyrosine and Luffa Cylindrica (Seed) Oil and Oleic acid ) by the company Sederma which contains extracts of pumpkin seeds (or Loofah oil), the product marketed under the brand name "Actibronze ™" >> (INCI name: hydrolyzed wheat protein and acetyl tyrosin e and copper gluconate) by the company Alban Muller, the product marketed under the brand name Tyrostan ™ (name INCI: potassium caproyl tyrosine) by the company Synerga, the product marketed under the brand name Tyrosinol (name INCI: Sorbitan Isostearate, glyceryl oleate, caproyl Tyrosine) by the company Synerga, the product marketed under the brand name InstaBronze ™ (name INCI: Dihydroxyacetone and acetyl tyrosine and copper gluconate) marketed by the company Alban Muller, the product marketed under the brand name Tyrosilane ( INCI name: methylsilanol and acetyl tyrosine) by the company Exymol; peptides known for their melanogenesis activation effect, for example the product marketed under the brand name Bronzing SF Peptide powder (INCI name: Dextran and Octapeptide-5) by the company Infinitec Activos, the product marketed under the brand name Melitane (INCI name: Glycerin and Aqua and Dextran and Acetyl hexapeptide-1) comprising acetyl hexapeptide-1 known for its agonist action of alpha-MSH, the product marketed under the brand name Melatimes Solutions ™ (INCI name: Butylene glycol,
    Palmitoyl Tripeptide-40) by the company LIPOTEC, sugars and sugar derivatives, for example the product marketed under the brand name Tanositol ™ (INCI name: inositol) by the company Provital, the product marketed under the brand name Thalitan ™ (or Phycosaccharide ™ AG) by the company CODIF international (INCI name: Aqua and Hydrolyzed algin (Laminaria Digitata) and magnesium sulfate and manganese sulfate) containing an oligosaccharide of marine origin (guluronic acid and mannuronic acid chelated with magnesium and manganese ions ), the product marketed under the brand name Melactiva ™ (INCI name: Maltodextrin, Mucuna Pruriens Seed extract) by the company Alban Muller, compounds rich in flavonoids for example the product marketed under the brand name "Biotanning" (INCI name : Hydrolyzed citrus Aurantium dulcis fruit extract) by the company Silab and known to be rich in lemon flavonoids (hesperidin type es); agents intended for the treatment of hair and / or body hair, for example agents protecting the hair follicle melanocytes, intended to protect said melanocytes against the cytotoxic agents responsible for senescence and / or apoptosis of said melanocytes, such as agents mimicking the activity of DOPAchrome tautomerase chosen from those described in the European patent application published under number EP1515688 A2, synthetic molecules mimicking SOD, for example manganese complexes, antioxidant compounds, for example cyclodextrin derivatives , siliceous compounds derived from ascorbic acid, lysine or arginine pyrrolidone carboxylate, combinations of cinnamic acid and vitamin C diester and more generally those cited in the European patent application published under EP number 1,515,688 A2.
    As examples of antioxidant agents which can be combined with said self-reversible reverse latex as defined above in said compositions (F) and (G), there is EDTA and its salts, citric acid, acid tartaric, oxalic acid, BHA (butylhydroxyanisol), BHT (butylhydroxytoluene), tocopherol derivatives such as tocopherol acetate, mixtures of antioxidant compounds such as DISSOLVINE1 GL 47S marketed by the company Akzo Nobel under the INCI name: Tetrasodium Glutamate Diacetate.
    As examples of sunscreens which can be combined with said self-reversible reverse latex as defined above in said compositions (F) and (G), there are all those appearing in cosmetic directive 76/768 / EEC as amended annex VII.
    Among the organic sunscreens that can be combined with said self-reversible reverse latex as defined above in said compositions (F) and (G), there is the family of benzoic acid derivatives such as para- acids. aminobenzoic acid (PABA), in particular the monoglycerol esters of PABA, the ethyl esters of N, N25 propoxy PABA, the ethyl esters of Ν, Ν-diethoxy PABA, the ethyl esters of N, Ndimethyl PABA, the methyl esters of Ν, Ν -dimethyl PABA, butyl esters of N, Ndimethyl PABA; the family of anthranilic acid derivatives such as homomenthyl-N-acetyl anthranilate; the family of salicylic acid derivatives such as amyl salicylate, homomenthyl salicylate, ethylhexyl salicylate, phenyl salicylate, benzyl salicylate, p-isopropanolphenyl salicylate; the family of cinnamic acid derivatives such as ethylhexyl cinnamate, ethyl-4-isopropyl cinnamate, methyl-2,5-diisopropyl cinnamate, p-methoxypropyl cinnamate, p-methoxyisopropyl cinnamate , p-methoxyisoamyl cinnamate, p-methoxyoctyl cinnamate (pmethoxy 2-ethylhexyl cinnamate), p-methoxy 2-ethoxyethyl cinnamate, methoxycyclohexyl p-cinnamate, ethyl-a-cyano cinnamate -p-phenyl, 2-ethylhexyl-a-cyanoβ-phenyl cinnamate, glyceryl diparamethoxy mono-2-ethylhexanoyl cinnamate; the family of benzophenone derivatives such as 2,4-dihydroxybenzophenone, 2,2'dihydroxy-4-methoxybenzophenone, 2,2 ', 4,4'-tetrahydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone, 2 -hydroxy-4-methoxy-4'-methylbenzophenone, 2hydroxy-4-methoxybenzophenone-5-sulfonate, 4-phenylbenzophenone, 2-ethylhexyl-4'-phenylbenzophenone-2-5 carboxylate, 2-hydroxy-4- n-octyloxybenzophenone, 4-hydroxy-3-carboxybenzophenone; 3- (4'-methylbenzylidene) -d, l-camphor, 3 (benzylidene) -d, camphor, benzalkonium methosulfate camphor; urocanic acid, ethyl urocanate; the family of sulfonic acid derivatives such as 2-phenylbenzimidazole-5 sulfonic acid and its salts; the family of triazine derivatives such as hydroxyphenyl triazine, ethylhexyloxyhydroxyphenyl-4-methoxyphenyltriazine, 2,4,6-trianillino- (p-carbo-2'-ethylhexyl-1'-oxy) -1,3, 5-triazine, 4,4 - ((6 - (((1,1-dimethylethyl) amino) carbonyl) phenyl) amino) -1,3,5-triazine-2,4-diyl diimino) bis- (2 -ethylhexyl) ester of benzoic acid, 2-phenyl-5-methylbenzoxazole, 2,2'-hydroxy-5-methylphenylbenzotriazole, 2- (2'-hydroxy-5'-t-octylphenyl) benzotriazole, 2- (2'-hydroxy-5'méthyphényl) benzotriazole; ladibenzazine; dianisoylmethane, 4-methoxy-4-tbutylbenzoylmethane; 5- (3,3-dimethyl-2-norbornylidene) -3-pentan-2-one; the family of diphenylacrylate derivatives such as 2-ethylhexyl-2-cyano-3,3-diphenyl-2-propenoate, ethyl-2-cyano-3,3-diphenyl-2-propenoate; the family of polysiloxanes such as benzylidene siloxane malonate.
    Among the inorganic sunscreens, also called mineral screens, which can be associated with said self-reversible reverse latex as defined above in said compositions (F) and (G), there are titanium oxides, oxides of zinc, cerium oxide, zirconium oxide, yellow, red or black iron oxides, chromium oxides. These mineral screens can be micronized or not, have undergone or not surface treatments and may be presented in the form of aqueous or oily predispersions.
    A subject of the invention is finally the use of said composition (C e ), as defined above, as an agent for reversing a reverse latex of a crosslinked anionic polyelectrolyte (P) comprising for 100% by molar:
    (ai) - of a proportion greater than or equal to 30 mol% and less than or equal to 100 mol%, of monomeric units derived from 2-methyl acid 2 - [(1 -oxo 2-propenyl) amino] 1 -propanesulfonic in free or partially or totally salified acid form;
    (a 2 ) - optionally of a proportion greater than 0 mol% and less than or equal to 70 mol%, of monomeric units derived from at least one monomer chosen from the elements of the group consisting of acrylic acid, the methacrylic acid, 2-carboxyethyl acrylic acid, itaconic acid, maleic acid, 3-methyl 3 [(1-oxo 2-propenyl) amino] butanoic acid, the carboxylic function of said monomers being in acid form free, partially salified or totally salified and / or from the elements of the group consisting of (2-hydroxyethyl acrylate), (2,3-dihydroxy propyl acrylate), (2-hydroxy ethyl methacrylate) , (2,3-dihydroxypropyl) methacrylate, or vinyl pyrrolidone;
    (83) - of a proportion greater than 0 mol% and less than or equal to 1 mol% of monomeric units derived from at least one diethylenic or polyethylene crosslinking monomer (AR);
    the sum of said molar proportions in monomeric units according to ai), a 2 ) and a 3 ) being equal to 100% molar;
    said reverse latex being a water-in-oil type emulsion (E) comprising for 100% of its mass:
    a) - from 10% by mass to 90% by mass, of said crosslinked anionic polyelectrolyte (P);
    b) - From 5% by mass to 50% by mass, of a fatty phase consisting of at least one oil (H),
    c) - From 1% by mass to 50% by mass of water, and
    d) - From 0.5% by mass to 10% by mass of an emulsifier system of the water-oil type (Si).
    the sum of the mass proportions of compounds according to a), b), c) and d) being equal to 100% by mass.
    The following examples illustrate the invention without, however, limiting it.
    I- Preparation of surfactant compositions according to the invention and comparatives
    Ia- Preparation of a composition comprising glyceryl polyglucoside and glycerol
    650 grams of glycerol, or 5 molar equivalents, are introduced into a jacketed glass reactor, in which a heat transfer fluid circulates, and provided with effective stirring. The glycerol is brought to a temperature of around 100 ° C.
    423.9 grams, or a molar equivalent, of glucose are then gradually added to the reaction medium to allow its homogeneous dispersion. An acid catalytic system consisting of 0.51 grams of 98% sulfuric acid is added to the mixture thus obtained.
    The reaction medium is placed under a partial vacuum at 30 mbar, and maintained at a temperature of 100 ° C-105 ° C for a period of four hours, with evacuation of the water formed by means of a distillation assembly.
    The reaction medium is then cooled to 95 ° C-100 ° C and neutralized by adding 30% sodium hydroxide, to bring the pH of a 1% solution of this mixture to a value of about 7.0.
    The reaction mixture is drained to obtain the composition referenced (Eib).
    The analytical characteristics of the composition (Eib) thus obtained are the following:
    Appearance (visual): clear liquid;
    pH solution at 1%: 6.8;
    Residual glycerol: 55.1%; Residual glucose: <1%;
    Glyceryl polyglucosides: 44.7%
    Ib- Preparation of the composition (EM 2 ) based on decaglycerol laurate (ΕΜ Ί ) and hexaglycerol
    71.5 grams of decaglycerol monolaurate marketed under the brand name DECAGLYN 1-L (below designated by the term) are introduced into a double-jacketed glass reactor, in which a heat transfer fluid circulates, and provided with effective mechanical stirring. "Composition (EMi)"), and 28.5 grams of polyglycerol6 (sold under the brand name Polyglycerol6 ™ by the company SPIGA), at a temperature of 35 ° C. under mechanical agitation of anchor type at a speed of 80 revolutions /minute. After mixing under such conditions for 30 minutes, the mixture is drained to obtain the composition (EM 2 ).
    the- Preparation of the composition (EM 3 ) based on decaglycerol laurate (EMi) and decaglycerol
    71.5 grams of decaglycerol monolaurate marketed under the brand name DECAGLYN 1-L (below designated by the term) are introduced into a double-jacketed glass reactor, in which a heat transfer fluid circulates, and provided with effective mechanical stirring. "Composition (EMi)"), and 28.5 grams of polyglycerol10 (sold under the brand name Polyglycerin 10 ™), at a temperature of 35 ° C. with mechanical stirring of the anchor type at a speed of 80 revolutions / minute . After mixing under such conditions for 30 minutes, the mixture is drained to obtain the composition (EM 3 ).
    Id- Preparation of the composition (EM 4 ) based on decaglycerol laurate (EMi), glyceryl polyglucoside and glycerol (Eib)
    71.5 grams of decaglycerol monolaurate marketed under the brand name DECAGLYN 1-L (hereinafter designated by the term) are introduced into a double-jacketed glass reactor, in which a heat transfer fluid circulates, and provided with effective mechanical stirring. “Composition (EMi) >>), and 28.5 grams of the composition (Eib), the preparation of which is described above, at a temperature of 35 ° C. under mechanical agitation of the anchor type at a speed of 80 revolutions /minute. After mixing under such conditions for 30 minutes, the mixture is drained to obtain the composition (EM 4 ).
    Ie- Preparation of the composition (EM 5 ) based on decaglycerol laurate (EMi) and glycerol
    71.5 grams of decaglycerol monolaurate marketed under the brand name DECAGLYN 1-L (below designated by the term) are introduced into a double-jacketed glass reactor, in which a heat transfer fluid circulates, and provided with effective mechanical stirring. "Composition (EMi)"), and 28.5 grams of glycerol, at a temperature of 35 ° C. with mechanical stirring of anchor type at a speed of 80 revolutions / minute. After mixing under such conditions for 30 minutes, the mixture is drained to obtain the composition (EM 5 ).
    The analytical characteristics of the compositions (EMi), (EM 2 ), (EM 3 ), (EM 4 ), (EM 5 ) and (EM 6 ) are recorded in Table 1 below.
    Table 1
    Emulsifying composition(EMi) (EM 2 ) (EM 3 ) (EM 4 ) (EM 5 ) Component proportions (% by mass)Decaglycerol monolaurate 100% 71.5% 71.5% 71.5% 71.5% Mass proportion of hexaglycerol 0% 28.5 0% 0% 0% Mass proportion of decaglycerol 0% 0% 28.5 0% 0% Mass proportion of glyceryl polyglucoside 0% 0% 0% 12.8% 0% Mass proportion of glycerol 0% 0% 0% 15.7% 28.5
    II - Preparation and evaluation of self-reversible reverse latexes of a crosslinked copolymer of the sodium salt of 2-methyl acid - [(1-oxo-2-propenyl) amino] 1-pro5 panesulfonic acid and acrylic acid partially salified.
    An aqueous phase is prepared by pouring successively into a beaker and with stirring 75.4 grams of glacial acrylic acid, 577.5 grams of a 55% aqueous solution of 2-methyl acid sodium salt - [(1 -oxo-2-propenyl) amino] 1-propanesulfonic, 42.5 grams of a 48% by weight aqueous sodium hydroxide solution, 0.45 grams of a 40% by weight commercial aqueous solution of diethylenetriamine penta-sodium acetate and 0.167 gram of methylene bis (acrylamide). The pH of this aqueous phase is then adjusted to 5.5.
    An organic phase is independently prepared by mixing 208 grams of the mixture of alkanes sold under the brand name Emogreen ™ L15, 14 15 grams of Montané ™ 80, 9.5 grams of Montané ™ 70 and 0.2 grams of azo bis (isobutyronitryl) (AIBN).
    The prepared aqueous phase is then gradually added to the oily phase and then dispersed using an Ultra Turrax type rotor stator sold by the company Ika.
    The emulsion obtained is transferred to a reactor to be subjected to a nitrogen sparge to remove the oxygen and cooled to approximately 5-6 ° C. 5 crrf of a solution at 0.42% by mass of cumene hydroperoxide in Emogreen ™ L15 are added to the emulsion maintained with stirring, then an aqueous solution at 0.1% by mass of sodium metabisulfite is gradually introduced at a flow rate of 0.5 cm 3 per minute to initiate the polymerization reaction. The temperature of the medium increases until it reaches a plateau. The reaction medium is then heated to 85 ° C for one hour and then the whole is cooled to about 35 ° C to obtain the mixture noted (M 2 ).
    The mixture (M 2 ) previously obtained is divided into different portions to which are added the different surfactant compositions (EMi), (EM 2 ), (EM 3 ), (EM 4 ) and (EM 5 ), as described above. , previously heated to 60 ° C, in mass proportions as indicated in Table 2 below.
    The self-reversible reverse latexes resulting from these mixtures are respectively denoted (Lh), (Ll 2 ), (Ll 3 ), (Ll 4 ) and (Ll 5 ), and are evaluated by observing their appearance at 25 °. C, by the inversion rate during the preparation of an aqueous gel at 2% by mass of self-reversible reverse latex, by the viscosity of this aqueous gel at 2% by mass of a self-reversible reverse latex.
    The method for evaluating the inversion time of self-reversing reverse latexes consists in introducing into a 2-liter beaker, the amount of water necessary for the preparation of an aqueous gel of 800 grams. A mechanical agitator propeller of the Turbotest ™ type, version 2004 marketed by the company VMI, is connected to the bottom of the beaker, connected to a motor. Stirring is started at a speed of 900 revolutions / minute and the necessary quantity of self-reversible reverse latex to be evaluated is introduced into the beaker with stirring. The agitation creates a vortex which disappears when the polymer reverses and the gel forms. The inversion time, measured in seconds, of the self-reversible reverse latexes corresponds to the time elapsed between the start of the addition of the tested self-reversible reverse latex and the disappearance of the vortex, leading to the production of a smooth gel. , free of lumps. This evaluation is carried out after the manufacture of the reverse latexes tested (t = 0), then after a storage period of 3 months at 25 ° C (t = 3 months). The results obtained are reported in Table 2 below. The viscosity of an aqueous gel at 2% by mass of self-reversible reverse latex (μ), is measured at t = 0 then at t = 3 months, using a Brookfield RVT viscometer (Mobile 6 Speed 5). Likewise, the appearance of the self-reversible reverse latex is evaluated visually at t = 0.
    Table 2
    Self-reversing reverse latexes(Lh) (Lk) (Lily) (READ) (Lily)Reference of the surfactant composition tested(EMi) (EM 2 ) (EM 3 ) (EM 4 ) (EM 5 ) Quantity tested (EMi) / (Lli) (% by mass) 5% 7% 7% 7% 7%Measures at t = 0 μ (in mPas) 120.000 116.000 104.000 98.000 104.000 Inversion time 130s 38s 38s 60s 16s Self-reversible latex appearance at 25 ° C Ell* Ell* Bl * Ell* Ell*Measurements at T = 3 months (3M) μ (in mPas) 97,000 98,000 100,000 94,000 95,000 Inversion time 151s 55s 78s 78s 17s
    Ell *: Liquid milky emulsion
    The self-reversible reverse latexes (L1 2 ), (L1 3 ), (L1 4 ) and (L1 5 ) according to the invention, and free of alkoxylated and more particularly ethoxylated derivatives, make it possible to obtain 5 smooth gels, with an inversion time much lower than that observed for the self-inverting reverse latex (Lh), comprising only the decaglycerol monolaurate alone as a constituent of the inverting surfactant system, while retaining excellent thickening properties. In addition, they are characterized by better reproducibility of the inversion rate and thickening properties after three months of storage than for the comparative self-reversible reverse latex (Lh).
    III - Preparation and evaluation of self-reversible reverse latexes of a crosslinked copolymer of the sodium salt of 2-methyl - [(1-oxo-2-propenyl) amino] 1-propanesulfonic acid and partially acrylic acid salified.
    Example II, described above, is reproduced, replacing the 208 grams of Emogreen ™ L15 with 208 grams of isohexadecane, to obtain the mixture noted (M 3 ), which is divided into different portions to which the different surfactant compositions (EMi), (EM 2 ) and (EM 3 ), as described above, previously heated to 60 ° C., in mass proportions as indicated in table 3 below. The self-reversible reverse latexes resulting from these mixtures are respectively denoted (L1 6 ), (L1 7 ) and (L1 8 ), and are evaluated by observing their appearance at 25 ° C., by the rate of inversion during of the preparation of an aqueous gel at 2% by mass of self-reversible reverse latex (the method of which is described above), by the viscosity 10 of this aqueous gel at 2% by mass of a self-reversible latex reversible (μ; Brookfield RVT viscometer (Mobile 6 Speed 5)). This evaluation is carried out after the manufacture of the reverse latexes tested (t = 0), then after a storage period of 3 months at 25 ° C (t = 3 months).
    The results obtained are reported in Table 3 below.
    Table 3
    Self-reversing reverse latexes(Lie) (LL) (Lie)Surfactant composition tested(EMi) (EM 2 ) (EM 3 ) Quantity tested (EMi) / (Lli) (% by mass) 5% 7% 7%Measures at t = 0 μ (in mPas) 108,000 106,000 110,000 Inversion time 125 s 60s 25s Self-reversible latex appearance at 25 ° C Ell* Ell* El *Measures at t = 3 months μ (in mPas) 97,000 102,000 105,000 Inversion time 155s 70s 72s
    Ell *: Liquid milky emulsion
    The self-inverting reverse latexes (L1 7 ) and (L1 8 ) according to the invention, and free of alkoxylated and more particularly ethoxylated derivatives, make it possible to obtain smooth gels, with a duration of inversion much lower than that observed for self-reversible reverse latex (L1 6 ), comprising only the only decaglycerol monolaurate as a constituent of the reversing surfactant system, while retaining excellent thickening properties. In addition, they are characterized by better reproducibility of the inversion rate and thickening properties after three months of storage than for the comparative self-reversible reverse latex (Lh).
    IV: Illustrative cosmetic formulations
    In the following formulations, the percentages are expressed in percentage by mass per 100% of the mass of the formulation.
    Example IV-1: Care CreamCyclomethicone: 10% Self-reversible reverse latex (Ll 2 ): 0.8% Montanov ™ 68: 2% Stearyl alcohol: 1% Stearic alcohol: 0.5% Conservative : 0.65% Lysine: 0.025% EDTA (disodium salt): 0.05% Xanthan gum: 0.2% Glycerin: 3% Water: q.s.p. 100%
    Example IV-2: Sun milk
    FORMULA
    At Montanov ™ 68: 3.0% Sesame oil : 5.0% PARSOL ™ MCX: 5.0% Carrageenan λ: 0.10% Beautiful : q.s. 100% C Self-reversible reverse latex (Ll 3 ): 0.80% D Perfume: qs
    Conservative :
    OPERATING MODE
    qs
    Emulsify B in A at 60 ° C then add C around 60C, then D around 30 ° C and adjust the pH if necessary.
    Example IV-3: Body milk
    Montanov ™ 202: 3.5% LANOL ™ 37T: 8.0% SOLAGUM ™ L: 0.05% Water: q.s. 100% Benzophenone-3: 2.0% Dimethicone 350cPs: 0.05% Self-reversible reverse latex (Ll 2 ): 2.5% Conservative : 0.2% Perfume: 0.4%
    Example IV-4: Makeup Removing Emulsion with Sweet Almond Oil
    Montanov ™ 202: 5%
    Sweet almond oil: 5%
    Water: q.s.p. 100%
    Self-reversible reverse latex (LL 2 ): 0.3%
    Glycerin: 5%
    Preservative: 0.2%
    Perfume: 0.3%
    Example IV-5: Moisturizing Cream for Oily Skin Montanov ™ 68: 5% Cetylstearylctanoate: 8% Octyl palmitate: 2% Water: q.s. 100% Self-reversible reverse latex (Ll 4 ): 2.6% MICROPEARL ™ M100: 3.0% Mucopolysaccharides: 5% SEPICIDE ™ HB: 0.8% Perfume: 0.3%
    Example IV-6: Cleansing milkMontanov ™ 68: 3% PRIMOL ™ 352: 8.0% Sweet almond oil: 2% Water: q.s. 100% Self-reversible reverse latex (Ll 2 ): 0.8% Conservative : 0.2% Example IV-7: Sun milkMontanov ™ L: 3.5% LANOL ™ 37T: 10.0% PARSOL ™ MCX: 5.0% EUSOLEX ™ 4360: 2.0% Water: q.s. 100% Self-reversible reverse latex (Ll 2 ): 1.8% Conservative : 0.2% Perfume: 0.4% Example IV-8: Sunless Tanning EmulsionLANOL ™ 99: 15% Montanov ™ 68: 3.0% PARSOL ™ MCX: 3.0% Water: q.s. 100% Dihydroxyacetone: 5.0% Monosodium phosphate: 0.2% Self-reversible reverse latex (Ll 5 ): 2.5% Perfume: 0.3% SEPICIDE ™ HB: 0.8% Sodium hydroxide : qs pH = 5. Example IV-9: Care CreamCyclomethicone: 10% Self-reversible reverse latex (Ll 4 ): 2.8% Montanov ™ 202: 4.5%
    Conservative : 0.65% Lysine: 0.025% EDTA (disodium salt): 0.05% Xanthan gum: 0.2% Glycerin: 3% Water: qs. 100% Example IV-10: SunscreenSIMULSOL ™ 165: 3% Montanov ™ 68: 2% Benzoate C12-C15: 8% PECOSIL ™ PS 100: 2% Dimethicone: 2% Cyclomethicone: 5% Octyl para-methoxy cinnamate: 6% Benzophenone-3: 4% Titanium oxide: 8% Xanthan gum : 0.2% Butylene glycol: 5% Demineralized Water : qs 100% Self-reversible reverse latex (Ll 2 ): 1.5% Preservative, fragrance: qs Example IV-11: Sun gel and self-tannerMontanov ™ 68: 3.0% Glyceryl triheptanoate: 10.0% DEEPALINE ™ PVB: 1.05% Self-reversible reverse latex (Ll 2 ): 2.2% Water: qs 100% Dihydroxyacetone: 5% Perfume: 0.1% SEPICIDE ™ HB: 0.3% 30 SEPICIDE ™ Cl: 0.1% PARSOL ™ MCX: 4.0%
    The definitions of the products used in the examples are as follows:
    MICROPEARL ™ Μ 100 is an ultra fine powder with a very soft touch and mattifying action sold by the company MATSUMO
    SEPICIDE ™ Cl, imidazolidine urea, is a preservative sold by the company SEPPIC.
    SIMULSOL ™ 165 is self-emulsifiable glycerol stearate sold by the company SEPPIC.
    SEPICIDE ™ HB, which is a mixture of phenoxyethanol, methylparaben, ethylparaben, propylparaben and butylparaben, is a preservative sold by the company SEPPIC.
    PARSOL ™ MCX is octyl para-methoxy cinnamate; marketed by the company GIVAUDAN.
    LANOL ™ 37T is glycerol triheptanoate, sold by the company SEPPIC. SOLAGUM ™ L is a carrageenan sold by the company SEPPIC.
    EUSOLEX ™ 4360 is a solar filter sold by the company MERCK. DEEPALINE ™ PVB, is a hydrolyzate of acylated wheat proteins marketed by the company SEPPIC.
    PRIMOL ™ 352 is a mineral oil sold by the company EXXON. PECOSIL ™ PS 100 is Dimethicone PEG-7 sold by the company PHOENIX.
    Montanov ™ 68 (INCI name Cetearyl Alcohol (and) Cetearyl Glucoside) is an emulsifying agent sold by the company SEPPIC
    Montanov ™ L (INCI name C14-22 Alcohols (and) C12-20 Alkyl Glucoside) is an emulsifying agent sold by the company SEPPIC.
    Montanov ™ 202 (INCI name Arachidyl Alcohol & Behenyl Alcohol & Arachidyl)) is an emulsifying agent sold by the company SEPPIC.
    权利要求:
    Claims (16)
    [1" id="c-fr-0001]
    1. Self-reversible reverse latex of a crosslinked anionic polyelectrolyte (P) comprising, for 100% molar:
    (ai) - of a proportion greater than or equal to 30 mol% and less than or equal to 100 mol%, of monomeric units derived from 2-methyl acid 2 - [(1-oxo 2-propenyl) amino] 1 -propanesulfonic in free or partially or totally salified acid form;
    (a 2 ) - optionally of a proportion greater than 0 mol% and less than or equal to 70 mol%, of monomeric units derived from at least one monomer chosen from the elements of the group consisting of acrylic acid, the methacrylic acid, 2-carboxyethyl acrylic acid, itaconic acid, maleic acid, 3-methyl 3 [(1-oxo 2-propenyl) amino] butanoic acid, the carboxylic function of said monomers being in acid form free, partially salified or totally salified and / or from the elements of the group consisting of (2-hydroxyethyl acrylate), (2,3-dihydroxy propyl acrylate), (2-hydroxy ethyl methacrylate) , (2,3-dihydroxypropyl) methacrylate, or vinyl pyrrolidone;
    (as) - of a proportion greater than 0 mol% and less than or equal to 1 mol% of monomeric units derived from at least one diethylene or polyethylene crosslinking monomer (AR);
    the sum of said molar proportions in monomeric units according to ai), a 2 ) and 83) being equal to 100 mol%;
    said self-reversible reverse latex being a water-in-oil type emulsion (E) comprising for 100% of its mass:
    a) - from 10% by mass to 90% by mass, of said crosslinked anionic polyelectrolyte (P);
    b) - From 5% by mass to 50% by mass, of a fatty phase consisting of at least one oil (H),
    c) - From 1% by mass to 50% by mass of water,
    d) - From 0.5% by mass to 10% by mass of an emulsifier system of the water-oil (Si) type, and
    e) - From 2% by mass to 10% by mass of an emulsifying system of the oil-in-water type (S 2 );
    the sum of the mass proportions of compounds according to a), b), c), d) and e) being equal to 100% by mass;
    said self-reversible reverse latex being characterized in that said oil-in-water type emulsifying system (S 2 ) comprises for 100% of its mass:
    f) - A proportion greater than or equal to 50% by mass and less than or equal to 100% of a composition (Ce) which comprises for 100% of its mass:
    ei) - From 10% by mass to 60% by mass of at least one compound of formula (I):
    HO- [CH 2 -CH (OH) -CH 2 -O] n -H (I) wherein n represents an integer greater than or equal to one and less than or equal to fifteen;
    e 2 ) - From 40% by mass to 90% by mass of at least one compound of formula (II):
    R 1 - (C = O) - [O-CH 2 -CH (OH) -CH 2 ] p-OH (II), in which p, different or identical to n, represents an integer greater than or equal to one and less than or equal to fifteen; and in which the group Ri- (C = O) - represents a saturated or unsaturated, linear or branched aliphatic radical, comprising from six to twenty two carbon atoms, and optionally e 3 ) - Up to 30% by mass of at least a composition (Cn) represented by formula (III):
    HO- [CH 2 -CHOH-CH 2 -O-] q- (G) r -H (III), in which q different or identical to n, represents an integer greater than or equal to one and less than or equal to 3 , G represents the remainder of a reducing sugar and r represents a decimal number greater than or equal to 1.05 and less than or equal to 5.00, said composition (Cn) consisting of a mixture of the compounds of formulas (III), ( lll 2 ), (lll 3 ), (lll 4 ) and (lll 5 ):
    HO- [CH 2 -CHOH-CH 2 -O-] q -O- (G) iH (llh),
    HO- [CH 2 -CHOH-CH2-O-] q -O- (G) 2 -H (Ill 2 ),
    HO- [CH 2 -CHOH-CH 2 -O-] q -O- (G) 3 -H (lll 3 ),
    HO- [CH 2 -CHOH-CH 2 -O-] q -O- (G) 4 -H (Fig 4 ),
    HO- [CH2-CHOH-CH 2 -O-] q -O- (G) sH (Ill 5 ), in molar proportions as said compounds of formulas (llh), (Ill 2 ), (Ill 3 ), ( lll 4 ) and (I Ils) respectively equal to a b a 2 , a 3 , a 4 and a 5 , such that the sum (au a 2 + a 3 + a 4 + as) is equal to one, and that the sum (ai + 2a 2 + 3a 3 + 4a 4 + 5as) is equal to r;
    the sum of the mass proportions of compounds according to efi, e 2 ) and e 3 ) being equal to 100% by mass.
    [2" id="c-fr-0002]
    2. Self-reversible reverse latex as defined in claim 1, characterized in that said crosslinked anionic polyelectrolyte (P) is a homopolymer of 2methyl 2 - [(1-oxo 2-propenyl) amino] 1-propanesulfonic acid partially or totally salified in the form of sodium salt or ammonium salt, crosslinked with triallylamine and / or methylene-bis (acrylamide); a copolymer of 2-methyl 2 - [(1-oxo 2-propenyl) amino] 1-propanesulfonic acid and acrylic acid partially or totally salified in the form of sodium salt or ammonium salt, crosslinked by triallylamine and / or methylene-bis (acrylamide); a copolymer of 2-methyl 2 - [(1-oxo 2-propenyl) amino] 1-propanesulfonic acid (y) partially or totally salified in the form of the sodium salt, and of acrylic acid (δ) partially or totally salified in the form of sodium salt in a molar ratio (γ) / (δ) greater than or equal to 30/70 and less than or equal to 90/10; crosslinked with triallylamine and / or methylene-bis (acrylamide); or a copolymer of 2-methyl 2 - [(1-oxo 2-propenyl) amino] 1-propanesulfonic acid (y) partially or totally salified in the form of sodium salt, and acrylic acid (ô) partially or totally salified in the form of sodium salt in a molar ratio (y) / (ô) greater than or equal to 40/60 and less than or equal to 90/10, crosslinked by triallylamine and / or methylene-bis (acrylamide) .
    [3" id="c-fr-0003]
    3 Self-reversible reverse latex as defined in any one of claims 1 or 2, characterized in that in the formula (I) as defined above, n represents an integer greater than or equal to one and less than or equal to ten, and in that in formula (II) as defined above, p, identical or different from n, represents an integer greater than or equal to one and less than or equal to ten, and the group Ri- (C = O ) - is chosen from the octanoyl, decanoyl, ω-undecylenoyl, dodecanoyl, tetradecanoyl, hexadecanoyl, octadecanoyl, 9-octadecenoyl or 9,12-octadecadienoyl radicals.
    [4" id="c-fr-0004]
    4. Self-reversible reverse latex as defined in any one of claims 1 to 3, characterized in that in said emulsifier system of oil-in-water type (S 2 ) said composition (C e ) as defined above , consists of, for 100% of its mass:
    βι) - From 10% by mass to 60% by mass of at least one compound of formula (I) as defined above and e 2 ) - From 40% by mass to 90% by mass of at least one compound of formula (II) as defined above.
    [5" id="c-fr-0005]
    5. Self-reversible reverse latex as defined in any one of claims 1 to 3, characterized in that in the formula (III) as defined above, q is equal to one, G represents the remainder of the glucose and r represents a decimal number greater than or equal to 1.05 and less than or equal to 2.5.
    [6" id="c-fr-0006]
    6. Self-reversible reverse latex as defined in any one of claims 1, 2, 3 or 5, characterized in that in said emulsion-oil-in-water system (S2), said composition (C e ) such that defined above consists of, for 100% of its mass:
    ei) - From 5% by mass to 15% by mass of at least one compound of formula (I) as defined above, e 2 ) - From 60% by mass to 80% by mass of at least one compound of formula (II) as defined above, and θ3) - From 5% to 15% by mass of at least one composition (Cn) represented by formula (III) as defined above.
    [7" id="c-fr-0007]
    7. reverse latex as defined in any one of claims 1 to 6, characterized in that said emulsifying system of oil-in-water type (S 2 ) is said composition (C e ) as defined above.
    [8" id="c-fr-0008]
    8. Composition (C e ) which comprises for 100% of its mass:
    ei) - From 10% by mass to 60% by mass of at least one compound of formula (I):
    HO- [CH 2 -CH (OH) -CH 2 -O] n -H (I) wherein n represents an integer greater than or equal to one and less than or equal to fifteen;
    e 2 ) - From 40% by mass to 90% by mass of at least one compound of formula (II):
    R 1 - (C = O) - [O-CH 2 -CH (OH) -CH 2 ] P -OH (U), in which p, different or identical to n, represents an integer greater than or equal to one and less than or equal to fifteen and the group Ri- (C = O) - represents a saturated or unsaturated, linear or branched aliphatic radical, comprising from six to twenty-two carbon atoms, and optionally e 3 ) - Up to 30% mass of at least one composition (Cn) represented by the formula (III):
    HO- [CH2-CHOH-CH 2 -O-] q- (G) rH (lll), formula (lll) in which q, different or identical to n, represents an integer greater than or equal to one and less than or equal at 3, G represents the remainder of a reducing sugar and r represents a decimal number greater than or equal to 1.05 and less than or equal to 5.00, said composition (Or) consisting of a mixture of the compounds of formulas (llh) , (Ill 2 ), (lll 3 ), (lll 4 ) and (llls):
    HO-fCHz-CHOH-CHz-O-lq -O- (G)! - H (llh),
    HO-fCHz-CHOH-CH ^ O-Jq -O- (G) 2 -H (lll 2 ),
    HO- [CH2-CHOH-CH 2 -O-] q -O- (G) 3 -H (lll 3 ),
    HO-tCHs-CHOH-CHz-O-Jq -O- (G) 4 -H <lll 4 ),
    HO- [CH2-CHOH-CH 2 -O-] q -O- (G) 5 -H (III 5 ), in molar proportions as said compounds of formulas (llh), (III2), (III 3 ), (lll 4 ) and (IIls) respectively equal to a b a 2 , a3, a 4 and as, such that the sum ai + a2 + a3 + a4 + as is equal to one, and that the sum ai + 2a 2 + 3a 3 + 4a 4 + 5a 5 is equal to r;
    the sum of the mass proportions of compounds according to βι), β2) and e 3 ) being equal to 100% by mass.
    [9" id="c-fr-0009]
    9. Composition (C e ) as defined in claim 8, characterized in that in the formula (I) as defined above, n represents an integer greater than or equal to one and less than or equal to ten, and in that that in formula (II) as defined above, p, identical or different from n, represents an integer greater than or equal to one and less than or equal to ten, and the group Ri- (C = O) - is chosen from the octanoyl, decanoyl, ω-undecylenoyl, dodecanoyl, tetradecanoyl, hexadecanoyl, octadecanoyl, 9-octadecenoyl or 9,12-octadecadienoyl radicals.
    [10" id="c-fr-0010]
    10. Composition (C e ) as defined in any one of claims 8 or 9, characterized in that it consists, for 100% of its mass:
    ei) - From 10% by mass to 60% by mass of at least one compound of formula (I) as defined above and e 2 ) - From 40% by mass to 90% by mass of at least one compound of formula (II) as defined above.
    [11" id="c-fr-0011]
    11. Composition (C e ) as defined in any one of claims 8 or 9, characterized in that in the formula (III) as defined above, q is equal to one, G represents the remainder of the glucose and r represents a decimal number greater than or equal to 1.05 and less than or equal to 2.5.
    [12" id="c-fr-0012]
    12. Composition (C e ) as defined in any one of claims 8, 9 or 11, characterized in that it consists, for 100% of its mass:
    and) - From 5% by mass to 15% by mass of at least one compound of formula (I) as defined above, e 2 ) - From 60% by mass to 80% by mass of at least one compound of formula (II) as defined above, and e 3 ) - From 5% to 15% by mass of at least one composition (Cn) represented by formula (III) as defined above.
    [13" id="c-fr-0013]
    13. Use of said self-reversible reverse latex as defined in one of claims 1 to 7, as a thickening and / or emulsifier and / or stabilizer of a topical cosmetic composition.
    [14" id="c-fr-0014]
    14. Topical cosmetic composition (F), characterized in that it comprises, as thickening agent, for 100% of its total mass between 0.1% and 10% by mass of said self-reversible reverse latex, as defined in one of claims 1 to 7.
    [15" id="c-fr-0015]
    15. Topical pharmaceutical composition (G) characterized in that it comprises as thickening agent, for 100% of its total mass between 0.1% and 10% by mass of said self-reversible reverse latex as defined in one of claims 1 to 7.
    [16" id="c-fr-0016]
    16. Use of said composition (C e ), as defined in any one of claims 8 to 12, as an agent for reversing a reverse latex of a crosslinked anionic polyelectrolyte (P) comprising for 100% by molar:
    (ai) - of a proportion greater than or equal to 30 mol% and less than or equal to 100 mol%, of monomeric units derived from 2-methyl acid 2 - [(1-oxo 2-propenyl) amino] 1 -propanesulfonic in free or partially or totally salified acid form;
    (a 2 ) - optionally of a proportion greater than 0 mol% and less than or equal to 70 mol%, of monomeric units derived from at least one monomer chosen from the elements of the group consisting of acrylic acid, the methacrylic acid, 2-carboxyethyl acrylic acid, itaconic acid, maleic acid, 3-methyl 3 [(1-oxo 2-propenyl) amino] butanoic acid, the carboxylic function of said monomers being in acid form free, partially salified or totally salified and / or from the elements of the group consisting of (2-hydroxyethyl acrylate), (2,3-dihydroxy propyl acrylate), (2-hydroxy ethyl methacrylate) , (2,3-dihydroxypropyl) methacrylate, or vinyl pyrrolidone;
    (a 3 ) - of a proportion greater than 0 mol% and less than or equal to 1 mol% of monomeric units derived from at least one diethylene or polyethylene crosslinking monomer (AR);
    the sum of said molar proportions in monomeric units according to ai), a 2 ) and a 3 ) being equal to 100% molar;
    said reverse latex being a water-in-oil type emulsion (E) comprising for 100% of its mass:
    a) - from 10% by mass to 90% by mass, of said crosslinked anionic polyelectrolyte (P);
    b) - From 5% by mass to 50% by mass, of a fatty phase consisting of at least one oil (H),
    c) - From 1% by mass to 50% by mass of water, and
    d) - From 0.5% by mass to 10% by mass of an emulsifier system of the water-oil type (Si).
    the sum of the mass proportions of compounds according to a), b), c) and d) being equal to 100% by mass.
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    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    US6375959B1|1998-02-17|2002-04-23|Societe D'exploitation De Produits Pour Les Industries Chimiques Seppic|Thickening homopolymer, preparation process and cosmetic applications|
    EP1055451A1|1999-05-28|2000-11-29|Societe D'exploitation De Produits Pour Les Industries Chimiques, S.E.P.P.I.C.|Use of alkylglycosides as inverter of polymer emulsions, method of inverting them, self-invertible inverted latex and industrial use thereof|
    WO2009156691A2|2008-06-27|2009-12-30|Société d'Exploitation de Produits pour les Industries Chimiques SEPPIC|Novel inverse latices that are free of oxyethylene derivatives, and cosmetic, dermocosmetic, dermopharmaceutical or pharmaceutical compositions comprising same|
    US20110076245A1|2008-06-27|2011-03-31|Societe D"exploitation De Produits Pour Les Industries Chimiques Seppic|Novel inverse latices that are free of oxyethylene derivatives, and cosmetic, dermocosmetic, dermopharmaceutical or pharmaceutical compositions comprising same|
    US20110098364A1|2008-06-27|2011-04-28|Societe D'exploitation De Produits Pour Les Industries Chimiques Seppic|Novel inverse latices based on fatty alcohol ethers, and cosmetic, dermocosmetic, dermopharmaceutical or pharmaceutical compositions comprising|
    JP3365422B2|1992-07-28|2003-01-14|三菱化学株式会社|Method for producing high-purity polyglycerin fatty acid ester|
    FR2721607B1|1994-06-28|1996-10-31|Seppic Sa|New quaternary ammonium derivatives, their preparation process and their use as surfactants.|
    FR2761595B1|1997-04-04|1999-09-17|Oreal|COMPOSITIONS COMPRISING SANTALINES, SANTARUBINS FOR ARTIFICIAL COLORING OF THE SKIN AND USES THEREOF|
    FR2794124B1|1999-05-28|2003-03-21|Seppic Sa|NOVEL INVERSE AUTO INVERSIBLE LATEX, PREPARATION METHOD AND USE IN COSMETICS|
    FR2810883B1|2000-06-28|2006-07-28|Seppic Sa|NOVEL AUTOINVERSIBLE INVERSE LATEX ON FATTY ACID ESTERS, COSMETIC, DERMOCOSMETIC, DERMOPHARMACEUTICAL OR PHARMACEUTICAL COMPOSITIONS COMPRISING THE SAME|
    WO2003103616A2|2002-06-11|2003-12-18|L'oreal|Use of an agent mimicking dopachrome tautomerase activity as protective agent for hair follicle melanocytes and uses thereof|
    JP5689322B2|2010-09-27|2015-03-25|株式会社ファンケル|Emulsified composition|
    US20210251864A1|2018-09-05|2021-08-19|Symrise Ag|Eco emulsifier|FR3104161B1|2019-12-09|2021-12-17|Soc Dexploitation De Produits Pour Les Industries Chimiques Seppic|Inverse latex for cosmetic composition comprising a particular sequestering agent and a polyelectrolyte combining strong acid function and weak acid function|
    FR3104157B1|2019-12-09|2021-12-10|Soc Dexploitation De Produits Pour Les Industries Chimiques Seppic|Inverse latex for cosmetic composition combining a particular sequestering agent and a polyelectrolyte comprising a weak acid function|
    法律状态:
    2019-03-22| PLFP| Fee payment|Year of fee payment: 2 |
    2019-09-13| PLSC| Publication of the preliminary search report|Effective date: 20190913 |
    2020-03-19| PLFP| Fee payment|Year of fee payment: 3 |
    2021-03-23| PLFP| Fee payment|Year of fee payment: 4 |
    优先权:
    申请号 | 申请日 | 专利标题
    FR1851933|2018-03-06|
    FR1851933A|FR3078709B1|2018-03-06|2018-03-06|SELF-REVERSIBLE SELF-REVERSIBLE REVERSE LATEX COMPRISING AS A REVERSE AGENT FOR SURFACTANT SPECIES OF THE POLYGLYCEROL ESTER FAMILY, AND COMPOSITIONS COMPRISING SAME|FR1851933A| FR3078709B1|2018-03-06|2018-03-06|SELF-REVERSIBLE SELF-REVERSIBLE REVERSE LATEX COMPRISING AS A REVERSE AGENT FOR SURFACTANT SPECIES OF THE POLYGLYCEROL ESTER FAMILY, AND COMPOSITIONS COMPRISING SAME|
    US16/977,568| US20210007962A1|2018-03-06|2019-02-27|Thickening self-invertible inverse latex comprising, as an inverting agent, surfactant species of the polyglycerol ester family, and compositions containing same|
    EP19715967.6A| EP3762433A1|2018-03-06|2019-02-27|Thickening self-invertible inverse latex comprising, as an inverting agent, surfactant species of the polyglycerol ester family, and compositions containing same|
    KR1020207027371A| KR20200130328A|2018-03-06|2019-02-27|Thickening self-reversible inverse latex comprising surfactant species of the polyglycerol ester family as a reversing agent, and a composition containing the same|
    PCT/FR2019/050443| WO2019170979A1|2018-03-06|2019-02-27|Thickening self-invertible inverse latex comprising, as an inverting agent, surfactant species of the polyglycerol ester family, and compositions containing same|
    JP2020545495A| JP2021515830A|2018-03-06|2019-02-27|As a reversing agent, a thickening self-reversible reverse latex containing a polyglycerol ester-based surfactant species, and a composition containing the same.|
    CN201980025329.4A| CN111971315A|2018-03-06|2019-02-27|Thickened self-reversible inverse latex comprising surfactant species of the polyglycerol ester family as inverse agent, and compositions containing same|
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